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Equation of state of shock-compressed liquids : carbon dioxide and air

Equation-of-state data were measured for liquid carbon dioxide and air shock-compressed to pressures in the range 28–71 GPa (280–710 kbar) using a two-stage light-gas gun. The experimental methods are described. The data indicate that shock-compressed liquid CO2 decomposes at pressures above 34 GPa....

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Published in:	The Journal of chemical physics 1991-10, Vol.95 (7), p.5268-5272
Main Authors:	NELLIS, W. J, MITCHELL, A. C, REE, F. H, ROSS, M, HOLMES, N. C, TRAINOR, R. J, ERSKINE, D. J
Format:	Article
Language:	English
Subjects:	360603 - Materials- Properties AIR CARBON COMPOUNDS CARBON DIOXIDE CARBON OXIDES CHALCOGENIDES COMPRESSED AIR COMPRESSED GASES Condensed matter: structure, mechanical and thermal properties EQUATIONS EQUATIONS OF STATE Equations of state of specific substances Equations of state, phase equilibria, and phase transitions Exact sciences and technology FLUIDS GASES INTERMOLECULAR FORCES LIQUIDS MATERIALS SCIENCE OXIDES OXYGEN COMPOUNDS Physics SHOCK WAVES
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description	Equation-of-state data were measured for liquid carbon dioxide and air shock-compressed to pressures in the range 28–71 GPa (280–710 kbar) using a two-stage light-gas gun. The experimental methods are described. The data indicate that shock-compressed liquid CO2 decomposes at pressures above 34 GPa. Liquid air dissociates above a comparable shock pressure, as does liquid nitrogen. Theoretical intermolecular potentials are derived for CO2 from the data. The calculated shock temperature for the onset of CO2 decomposition is 4500 K at a volume of 17 cm3/mol.
doi_str_mv	10.1063/1.461665
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J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Equation of state of shock-compressed liquids : carbon dioxide and air</atitle><jtitle>The Journal of chemical physics</jtitle><date>1991-10-01</date><risdate>1991</risdate><volume>95</volume><issue>7</issue><spage>5268</spage><epage>5272</epage><pages>5268-5272</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><coden>JCPSA6</coden><abstract>Equation-of-state data were measured for liquid carbon dioxide and air shock-compressed to pressures in the range 28–71 GPa (280–710 kbar) using a two-stage light-gas gun. The experimental methods are described. The data indicate that shock-compressed liquid CO2 decomposes at pressures above 34 GPa. Liquid air dissociates above a comparable shock pressure, as does liquid nitrogen. Theoretical intermolecular potentials are derived for CO2 from the data. The calculated shock temperature for the onset of CO2 decomposition is 4500 K at a volume of 17 cm3/mol.</abstract><cop>Woodbury, NY</cop><pub>American Institute of Physics</pub><doi>10.1063/1.461665</doi><tpages>5</tpages></addata></record>
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source	American Institute of Physics (AIP) Publications
subjects	360603 - Materials- Properties AIR CARBON COMPOUNDS CARBON DIOXIDE CARBON OXIDES CHALCOGENIDES COMPRESSED AIR COMPRESSED GASES Condensed matter: structure, mechanical and thermal properties EQUATIONS EQUATIONS OF STATE Equations of state of specific substances Equations of state, phase equilibria, and phase transitions Exact sciences and technology FLUIDS GASES INTERMOLECULAR FORCES LIQUIDS MATERIALS SCIENCE OXIDES OXYGEN COMPOUNDS Physics SHOCK WAVES
title	Equation of state of shock-compressed liquids : carbon dioxide and air
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