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X-Ray diffraction study of liquid n-butane at 140 and 267 K

X-ray diffraction data for liquid n-butane near the triple and boiling points are presented. The data are analyzed using scattering factors for −CH3 and −CH2 groups which permits extraction of structure and distribution functions for carbon sites. An intramolecular carbon–carbon distance at approxim...

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Published in:	The Journal of chemical physics 1989-10, Vol.91 (7), p.4299-4306
Main Authors:	HABENSCHUSS, A, NARTEN, A. H
Format:	Article
Language:	English
Subjects:	400201 - Chemical & Physicochemical Properties ALKANES BOILING POINTS BUTANE COHERENT SCATTERING Condensed matter: structure, mechanical and thermal properties DIFFRACTION DISTRIBUTION FUNCTIONS Exact sciences and technology FLUIDS FUNCTIONS HYDROCARBONS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LIQUIDS LOW TEMPERATURE MEDIUM TEMPERATURE ORGANIC COMPOUNDS PHYSICAL PROPERTIES Physics SCATTERING STRUCTURE FACTORS Structure of solids and liquids crystallography Studies of specific liquid structures THERMODYNAMIC PROPERTIES TRANSITION TEMPERATURE TRIPLE POINT X-RAY DIFFRACTION
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description	X-ray diffraction data for liquid n-butane near the triple and boiling points are presented. The data are analyzed using scattering factors for −CH3 and −CH2 groups which permits extraction of structure and distribution functions for carbon sites. An intramolecular carbon–carbon distance at approximately 3.1 Å is assigned to a short end-to-end distance in a near-gauche conformation, which is in agreement with the electron diffraction results for gaseous n-butane. The intermolecular pair distribution functions show a large difference in the liquid structure for the low and high temperature states, similar to that found in liquid propane.
doi_str_mv	10.1063/1.456810
format	article
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H</creatorcontrib><title>X-Ray diffraction study of liquid n-butane at 140 and 267 K</title><title>The Journal of chemical physics</title><description>X-ray diffraction data for liquid n-butane near the triple and boiling points are presented. The data are analyzed using scattering factors for −CH3 and −CH2 groups which permits extraction of structure and distribution functions for carbon sites. An intramolecular carbon–carbon distance at approximately 3.1 Å is assigned to a short end-to-end distance in a near-gauche conformation, which is in agreement with the electron diffraction results for gaseous n-butane. 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H</creator><general>American Institute of Physics</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19891001</creationdate><title>X-Ray diffraction study of liquid n-butane at 140 and 267 K</title><author>HABENSCHUSS, A ; NARTEN, A. 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H</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>HABENSCHUSS, A</au><au>NARTEN, A. H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>X-Ray diffraction study of liquid n-butane at 140 and 267 K</atitle><jtitle>The Journal of chemical physics</jtitle><date>1989-10-01</date><risdate>1989</risdate><volume>91</volume><issue>7</issue><spage>4299</spage><epage>4306</epage><pages>4299-4306</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><coden>JCPSA6</coden><abstract>X-ray diffraction data for liquid n-butane near the triple and boiling points are presented. The data are analyzed using scattering factors for −CH3 and −CH2 groups which permits extraction of structure and distribution functions for carbon sites. An intramolecular carbon–carbon distance at approximately 3.1 Å is assigned to a short end-to-end distance in a near-gauche conformation, which is in agreement with the electron diffraction results for gaseous n-butane. The intermolecular pair distribution functions show a large difference in the liquid structure for the low and high temperature states, similar to that found in liquid propane.</abstract><cop>Woodbury, NY</cop><pub>American Institute of Physics</pub><doi>10.1063/1.456810</doi><tpages>8</tpages></addata></record>
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source	American Institute of Physics (AIP) Publications
subjects	400201 - Chemical & Physicochemical Properties ALKANES BOILING POINTS BUTANE COHERENT SCATTERING Condensed matter: structure, mechanical and thermal properties DIFFRACTION DISTRIBUTION FUNCTIONS Exact sciences and technology FLUIDS FUNCTIONS HYDROCARBONS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LIQUIDS LOW TEMPERATURE MEDIUM TEMPERATURE ORGANIC COMPOUNDS PHYSICAL PROPERTIES Physics SCATTERING STRUCTURE FACTORS Structure of solids and liquids crystallography Studies of specific liquid structures THERMODYNAMIC PROPERTIES TRANSITION TEMPERATURE TRIPLE POINT X-RAY DIFFRACTION
title	X-Ray diffraction study of liquid n-butane at 140 and 267 K
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