Improved oxide ion conductivity in La[sub 0. 8]Sr[sub 0. 2]Ga[sub 0. 8]Mg[sub 0. 2]O[sub 3] by doping Co

• Published in: Chemistry of materials 1999-08, Vol.11:8
• Main Authors: Ishihara, Tatsumi, Furutani, Haruyoshi, Honda, Miho, Yamada, Takashi, Shibayama, Takaaki, Akbay, Taner, Takita, Yusaka, Sakai, Natsuko, Yokokawa, Harumi
• Format: Article
• Language: English
• Subjects: 360204 - Ceramics, Cermets, & Refractories- Physical Properties; ALKALINE EARTH METAL COMPOUNDS; CHALCOGENIDES; COBALT; ELECTRIC CONDUCTIVITY; ELECTRICAL PROPERTIES; ELEMENTS; GALLIUM COMPOUNDS; GALLIUM OXIDES; IONIC CONDUCTIVITY; LANTHANUM COMPOUNDS; LANTHANUM OXIDES; MAGNESIUM COMPOUNDS; MAGNESIUM OXIDES; MATERIALS SCIENCE; METALLURGICAL EFFECTS; METALS; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; RARE EARTH COMPOUNDS; STRONTIUM COMPOUNDS; STRONTIUM OXIDES; TRANSITION ELEMENTS
• ISSN: 0897-4756; 1520-5002
• DOI: 10.1021/cm981145w

The effects of doping Co for the Ga site on the oxide ion conductivity of La[sub 0.8]Sr[sub 0.2]Ga[sub 0.8]Mg[sub 0.2]O[sub 3] have been investigated in detail. It was found that doping Co is effective for enhancing the oxide ion conductivity. In particular, a significant increase in conductivity in the low-temperature range was observed. The electrical conductivity was monotonically increased; however, the transport number for the oxide ion decreased with an increasing amount of Co. Considering the transport number and ion transport number, an optimized amount for the Co doping seems to exist at 8.5 mol % for Ga site. The theoretical electromotive forces were exhibited on a H[sub 2]-O[sub 2] gas cell utilizing optimized composition of La[sub 0.8]Sr[sub 0.2]Ga[sub 0.8]Mg[sub 0.115]Co[sub 0.085]O[sub 3] (A). The diffusion characteristics of the oxide ion in A was also investigated by using the [sup 18]O tracer method. Since the diffusion coefficient measured by the [sup 18]O tracer method was similar to that estimated by the electrical conductivity, the conduction of A is concluded to be almost ionic. On the other hand, an oxygen permeation measurement suggests that the oxide ion conductivity increased linearly with an increasing amount of Co. Therefore, specimens with Co content higher than 10 mol% can be considered as a superior mixed oxide ion and hole conductor. The UV-vis spectra suggests that the valence number of doped Co was changed from +3 to +2 with decreasing oxygen partial pressure; the origin of hole conduction can thus be assigned to the formation of Co[sup 3+]. Since the amount of dopant in the Ga site was compensated with Mg[sup 2+], the amount of oxygen deficiency was decreased by doping Co. Therefore, it is likely that the improved oxide ion conductivity observed by doping with Co is brought about by the enhanced mobility of oxide ion.