Self-ignition of small-ring hydrocarbons behind reflected shock waves

Self-ignition of stoichiometric airlike argon mixtures of monocyclic and bicyclic small-ring hydrocarbons was investigated behind reflected shock waves at 1200–1600 K and 0.6 ± 0.1 MPa. The reactivity of small-ring hydrocarbons has been found to be determined by the properties of their thermal decom...

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Bibliographic Details
Published in:Combustion and flame 1993-07, Vol.94 (1), p.108-112
Main Authors: Slutsky, V.G., Kazakov, O.D., Severin, E.S., Bespalov, E.V., Tsyganov, S.A.
Format: Article
Language:English
Subjects:
400800 - Combustion, Pyrolysis, & High-Temperature Chemistry
ALKANES
CHEMICAL REACTIONS
COMBUSTION
COMBUSTION PROPERTIES
CYCLOALKANES
DECOMPOSITION
HYDROCARBONS
IGNITION
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
LOW PRESSURE
ORGANIC COMPOUNDS
OXIDATION
PROPELLANTS
PYROLYSIS
SHOCK WAVES
SPONTANEOUS COMBUSTION
TEMPERATURE RANGE
TEMPERATURE RANGE 1000-4000 K
THERMOCHEMICAL PROCESSES
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Summary:Self-ignition of stoichiometric airlike argon mixtures of monocyclic and bicyclic small-ring hydrocarbons was investigated behind reflected shock waves at 1200–1600 K and 0.6 ± 0.1 MPa. The reactivity of small-ring hydrocarbons has been found to be determined by the properties of their thermal decomposition products. New high-temperature decomposition channels for spiropentane, methylenecyclobutane, and methylenecyclopropane have been discovered.
ISSN:0010-2180
1556-2921
DOI:10.1016/0010-2180(93)90023-V