A novel copper(II) complex containing the ligand 1,2-bis(2,2'-bipyridyl-6-yl)ethane: structural, magnetic, redox, and spectral properties

The preparation of an open-ended ligand based on 2,2{prime}-bipyridine and a method for coordination of the ligand to copper(I) and copper(II) are reported. The specific ligand prepared was 1,2-bis(2,2{prime}-bipyridyl-6-yl)ethane. The x-ray structure of the copper(II) complex and the solid-state an...

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Bibliographic Details
Published in:Inorganic chemistry 1990-07, Vol.29 (15), p.2863-2868
Main Authors: Garber, Ty, Van Wallendael, Shawn, Rillema, D. Paul, Kirk, Martin, Hatfield, William E, Welch, Jane H, Singh, P
Format: Article
Language:English
Subjects:
400201 - Chemical & Physicochemical Properties
ABSORPTION SPECTRA
AZINES
BIPYRIDINES
CHEMICAL PREPARATION
CHEMISTRY
COHERENT SCATTERING
COMPLEXES
Condensed matter: structure, mechanical and thermal properties
Coordination compounds
COPPER COMPLEXES
DATA
DIFFRACTION
ELECTROCHEMISTRY
ELECTRON SPIN RESONANCE
ELECTRONIC STRUCTURE
Exact sciences and technology
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
INFORMATION
Inorganic chemistry and origins of life
Inorganic compounds
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
MAGNETIC PROPERTIES
MAGNETIC RESONANCE
MAGNETIC SUSCEPTIBILITY
Metal complexes
MOLECULAR STRUCTURE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHYSICAL PROPERTIES
Physics
Preparations and properties
PYRIDINES
RESONANCE
SCATTERING
SPECTRA
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION
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Summary:The preparation of an open-ended ligand based on 2,2{prime}-bipyridine and a method for coordination of the ligand to copper(I) and copper(II) are reported. The specific ligand prepared was 1,2-bis(2,2{prime}-bipyridyl-6-yl)ethane. The x-ray structure of the copper(II) complex and the solid-state and solution properties of the complexes are reported. 27 refs., 5 figs., 4 tabs.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic00340a028