The Dissolution of Calcite in Aqueous Acid: The Influence of Humic Species

The kinetics of proton-induced calcite dissolution in aqueous solution in the presence of humic acids and their sodium salts are reported. In equilibrated acid solutions (pH < 4) there is no inhibition by humic material and dissolution proceeds at a rate simply determined by the solution pH. Cont...

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Bibliographic Details
Published in:Journal of colloid and interface science 1993-07, Vol.158 (2), p.439-445
Main Authors: Compton, Richard G., Sanders, Giles H.W.
Format: Article
Language:English
Subjects:
540350 - Environment, Aquatic- Site Resource & Use Studies- (1990-)
ACID RAIN
ALKALI METAL COMPOUNDS
ATMOSPHERIC PRECIPITATIONS
BENCH-SCALE EXPERIMENTS
CALCITE
CARBONATE MINERALS
CARBOXYLIC ACID SALTS
CATALYTIC EFFECTS
Chemistry
DISSOLUTION
ENVIRONMENTAL SCIENCES
Exact sciences and technology
HUMIC ACIDS
Inorganic chemistry and origins of life
Kinetics and mechanism of reactions
LAKES
LIMING
MINERALS
MITIGATION
ORGANIC ACIDS
ORGANIC COMPOUNDS
PH VALUE
RAIN
SODIUM COMPOUNDS
SURFACE WATERS
WATER RECLAMATION
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Summary:The kinetics of proton-induced calcite dissolution in aqueous solution in the presence of humic acids and their sodium salts are reported. In equilibrated acid solutions (pH < 4) there is no inhibition by humic material and dissolution proceeds at a rate simply determined by the solution pH. Contrastingly the sodium salts of humic acids were found to have a significant inhibitory effect on the acid catalyzed dissolution. This was quantified using a novel channel flow cell experiment which employed two electrodes, the upstream of which was used to inject protons into a neutral solution, which also contained sodium salts of humic acid, via electrolytic oxidation of dissolved hydroquinone. The two electrodes were located immediately upstream and downstream of a calcite crystal so that the proton injection served to dissolve the calcite in the (inhibiting) presence of humic salts unequilibrated with the solution pH. The amount of H+ which survived passage to the downstream "detector" electrode was used to quantify the rate of dissolution and hence the inhibitory effects of the humic acid. The latter were found to operate in a manner not inconsistent with Langmuirian adsorption.
ISSN:0021-9797
1095-7103
DOI:10.1006/jcis.1993.1276