Loading…
Gasification of agricultural residues (biomass): influence of inorganic constituents
Four different biomass samples are included in this study, viz., sphagnum peat, wheat straw, sugar beet pulp, and potato pulp. They were chosen to represent a wide range of plant origin and inorganic content. This paper represents a preliminary investigation of an approach based on pyrolysis of biom...
Saved in:
| Published in: | Journal of agricultural and food chemistry 1990-01, Vol.38 (1), p.320-323 |
|---|---|
| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-a376t-2517c5804ba75aeb3ff18060a4186b6de9667a67ccd68d69296ea797073dc4963 |
|---|---|
| cites | |
| container_end_page | 323 |
| container_issue | 1 |
| container_start_page | 320 |
| container_title | Journal of agricultural and food chemistry |
| container_volume | 38 |
| creator | DeGroot, William F Kannan, M. Parambil Richards, Geoffrey N Theander, Olof |
| description | Four different biomass samples are included in this study, viz., sphagnum peat, wheat straw, sugar beet pulp, and potato pulp. They were chosen to represent a wide range of plant origin and inorganic content. This paper represents a preliminary investigation of an approach based on pyrolysis of biomass to produce volatile products and chars, followed by gasification of the chars. The particular interest lies in the investigation of the influence of the indigenous metal ions on the rate of gasification. Carbon dioxide has been used for the gasification, and the biomass was analyzed for nine metals, uronic acids (which are implicated in the binding of inorganic counterions), protein, and Klason lignin. The highest individual metal ion content was 13 964 ppm of potassium in potato pulp, and the gasification rates, under constant conditions, covered up to a 20-fold range, with char from potato pulp being the most readily gasified and char from peat the most resistant. The correlation of gasification rates with content of the major metal ions (alkali metals and alkaline earths) was poor. However, a high level of correlation was observed when wheat straw was omitted. It is speculate that the latter biomass may be anomalous with respect to the other three because of its high silica content |
| doi_str_mv | 10.1021/jf00091a070 |
| format | article |
| fullrecord | <record><control><sourceid>acs_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_6552243</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>b18170112</sourcerecordid><originalsourceid>FETCH-LOGICAL-a376t-2517c5804ba75aeb3ff18060a4186b6de9667a67ccd68d69296ea797073dc4963</originalsourceid><addsrcrecordid>eNpt0M1rFDEYBvBQWujaeurN0yBClTKazEw-pjcpbi0uftDtpZfwbiapWafJkjcD-t-bZaR46CmB55e8Lw8hZ4y-Z7RhH7aOUtozoJIekAXjDa05Y-qQLGiJa8UFOyYvELeFKS7pgqyvAb3zBrKPoYqugofkzTTmKcFYJYt-mCxWbzc-PgLiu8vKBzdONhi71z7E9ADBm8rEgNnnkmQ8JUcORrQv_50n5G75aX31uV59u765-riqoZUi1w1n0nBFuw1IDnbTOscUFRQ6psRGDLYXQoKQxgxCDaJvemFB9pLKdjBdL9oT8nr-N5bRGo3P1vwsiwRrshacN03XFnQxI5MiYrJO75J_hPRHM6r3ren_Wiv6zax3gAZGlyAYj09PhGKsa1hh9cw8Zvv7KYb0SwvZSq7X32_1l6_L-x9LVS7Fv5q9g6j3FaO-u-07ytpuP_N8DsGg3sYphVLas9v9Bd31j70</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Gasification of agricultural residues (biomass): influence of inorganic constituents</title><source>American Chemical Society</source><creator>DeGroot, William F ; Kannan, M. Parambil ; Richards, Geoffrey N ; Theander, Olof</creator><creatorcontrib>DeGroot, William F ; Kannan, M. Parambil ; Richards, Geoffrey N ; Theander, Olof</creatorcontrib><description>Four different biomass samples are included in this study, viz., sphagnum peat, wheat straw, sugar beet pulp, and potato pulp. They were chosen to represent a wide range of plant origin and inorganic content. This paper represents a preliminary investigation of an approach based on pyrolysis of biomass to produce volatile products and chars, followed by gasification of the chars. The particular interest lies in the investigation of the influence of the indigenous metal ions on the rate of gasification. Carbon dioxide has been used for the gasification, and the biomass was analyzed for nine metals, uronic acids (which are implicated in the binding of inorganic counterions), protein, and Klason lignin. The highest individual metal ion content was 13 964 ppm of potassium in potato pulp, and the gasification rates, under constant conditions, covered up to a 20-fold range, with char from potato pulp being the most readily gasified and char from peat the most resistant. The correlation of gasification rates with content of the major metal ions (alkali metals and alkaline earths) was poor. However, a high level of correlation was observed when wheat straw was omitted. It is speculate that the latter biomass may be anomalous with respect to the other three because of its high silica content</description><identifier>ISSN: 0021-8561</identifier><identifier>EISSN: 1520-5118</identifier><identifier>DOI: 10.1021/jf00091a070</identifier><identifier>CODEN: JAFCAU</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>09 BIOMASS FUELS ; 090900 - Biomass Fuels- Processing- (1990-) ; AGRICULTURAL WASTES ; Agronomy. Soil science and plant productions ; BEETS ; Biological and medical sciences ; BIOMASA ; BIOMASS ; BIOMASSE ; CARBON COMPOUNDS ; CARBON DIOXIDE ; CARBON OXIDES ; CATALYTIC EFFECTS ; CEREALS ; CHALCOGENIDES ; CHARS ; CHEMICAL REACTIONS ; DECHET AGRICOLE ; DECOMPOSITION ; DESECHOS AGRICOLAS ; ELEMENTS ; ENERGY SOURCES ; FLUIDS ; FOOD ; FOSSIL FUELS ; FUELS ; Fundamental and applied biological sciences. Psychology ; GASES ; GASIFICATION ; General agronomy. Plant production ; GRAMINEAE ; LILIOPSIDA ; MAGNOLIOPHYTA ; MAGNOLIOPSIDA ; METALS ; ORGANIC MATTER ; ORGANIC WASTES ; OXIDES ; OXYGEN COMPOUNDS ; PEAT ; PLANTS ; POTATOES ; PROCESAMIENTO ; PYROLYSIS ; PYROLYSIS PRODUCTS ; RENEWABLE ENERGY SOURCES ; SYNTHESIS GAS ; THERMOCHEMICAL PROCESSES ; TRAITEMENT ; TUBERS ; Use of agricultural and forest wastes. Biomass use, bioconversion ; VEGETABLES ; WASTES ; WHEAT</subject><ispartof>Journal of agricultural and food chemistry, 1990-01, Vol.38 (1), p.320-323</ispartof><rights>1990 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a376t-2517c5804ba75aeb3ff18060a4186b6de9667a67ccd68d69296ea797073dc4963</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jf00091a070$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jf00091a070$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,776,780,881,4010,27041,27900,27901,27902,56741,56791</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=6811421$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/6552243$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>DeGroot, William F</creatorcontrib><creatorcontrib>Kannan, M. Parambil</creatorcontrib><creatorcontrib>Richards, Geoffrey N</creatorcontrib><creatorcontrib>Theander, Olof</creatorcontrib><title>Gasification of agricultural residues (biomass): influence of inorganic constituents</title><title>Journal of agricultural and food chemistry</title><addtitle>J. Agric. Food Chem</addtitle><description>Four different biomass samples are included in this study, viz., sphagnum peat, wheat straw, sugar beet pulp, and potato pulp. They were chosen to represent a wide range of plant origin and inorganic content. This paper represents a preliminary investigation of an approach based on pyrolysis of biomass to produce volatile products and chars, followed by gasification of the chars. The particular interest lies in the investigation of the influence of the indigenous metal ions on the rate of gasification. Carbon dioxide has been used for the gasification, and the biomass was analyzed for nine metals, uronic acids (which are implicated in the binding of inorganic counterions), protein, and Klason lignin. The highest individual metal ion content was 13 964 ppm of potassium in potato pulp, and the gasification rates, under constant conditions, covered up to a 20-fold range, with char from potato pulp being the most readily gasified and char from peat the most resistant. The correlation of gasification rates with content of the major metal ions (alkali metals and alkaline earths) was poor. However, a high level of correlation was observed when wheat straw was omitted. It is speculate that the latter biomass may be anomalous with respect to the other three because of its high silica content</description><subject>09 BIOMASS FUELS</subject><subject>090900 - Biomass Fuels- Processing- (1990-)</subject><subject>AGRICULTURAL WASTES</subject><subject>Agronomy. Soil science and plant productions</subject><subject>BEETS</subject><subject>Biological and medical sciences</subject><subject>BIOMASA</subject><subject>BIOMASS</subject><subject>BIOMASSE</subject><subject>CARBON COMPOUNDS</subject><subject>CARBON DIOXIDE</subject><subject>CARBON OXIDES</subject><subject>CATALYTIC EFFECTS</subject><subject>CEREALS</subject><subject>CHALCOGENIDES</subject><subject>CHARS</subject><subject>CHEMICAL REACTIONS</subject><subject>DECHET AGRICOLE</subject><subject>DECOMPOSITION</subject><subject>DESECHOS AGRICOLAS</subject><subject>ELEMENTS</subject><subject>ENERGY SOURCES</subject><subject>FLUIDS</subject><subject>FOOD</subject><subject>FOSSIL FUELS</subject><subject>FUELS</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>GASES</subject><subject>GASIFICATION</subject><subject>General agronomy. Plant production</subject><subject>GRAMINEAE</subject><subject>LILIOPSIDA</subject><subject>MAGNOLIOPHYTA</subject><subject>MAGNOLIOPSIDA</subject><subject>METALS</subject><subject>ORGANIC MATTER</subject><subject>ORGANIC WASTES</subject><subject>OXIDES</subject><subject>OXYGEN COMPOUNDS</subject><subject>PEAT</subject><subject>PLANTS</subject><subject>POTATOES</subject><subject>PROCESAMIENTO</subject><subject>PYROLYSIS</subject><subject>PYROLYSIS PRODUCTS</subject><subject>RENEWABLE ENERGY SOURCES</subject><subject>SYNTHESIS GAS</subject><subject>THERMOCHEMICAL PROCESSES</subject><subject>TRAITEMENT</subject><subject>TUBERS</subject><subject>Use of agricultural and forest wastes. Biomass use, bioconversion</subject><subject>VEGETABLES</subject><subject>WASTES</subject><subject>WHEAT</subject><issn>0021-8561</issn><issn>1520-5118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNpt0M1rFDEYBvBQWujaeurN0yBClTKazEw-pjcpbi0uftDtpZfwbiapWafJkjcD-t-bZaR46CmB55e8Lw8hZ4y-Z7RhH7aOUtozoJIekAXjDa05Y-qQLGiJa8UFOyYvELeFKS7pgqyvAb3zBrKPoYqugofkzTTmKcFYJYt-mCxWbzc-PgLiu8vKBzdONhi71z7E9ADBm8rEgNnnkmQ8JUcORrQv_50n5G75aX31uV59u765-riqoZUi1w1n0nBFuw1IDnbTOscUFRQ6psRGDLYXQoKQxgxCDaJvemFB9pLKdjBdL9oT8nr-N5bRGo3P1vwsiwRrshacN03XFnQxI5MiYrJO75J_hPRHM6r3ren_Wiv6zax3gAZGlyAYj09PhGKsa1hh9cw8Zvv7KYb0SwvZSq7X32_1l6_L-x9LVS7Fv5q9g6j3FaO-u-07ytpuP_N8DsGg3sYphVLas9v9Bd31j70</recordid><startdate>19900101</startdate><enddate>19900101</enddate><creator>DeGroot, William F</creator><creator>Kannan, M. Parambil</creator><creator>Richards, Geoffrey N</creator><creator>Theander, Olof</creator><general>American Chemical Society</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19900101</creationdate><title>Gasification of agricultural residues (biomass): influence of inorganic constituents</title><author>DeGroot, William F ; Kannan, M. Parambil ; Richards, Geoffrey N ; Theander, Olof</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a376t-2517c5804ba75aeb3ff18060a4186b6de9667a67ccd68d69296ea797073dc4963</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>09 BIOMASS FUELS</topic><topic>090900 - Biomass Fuels- Processing- (1990-)</topic><topic>AGRICULTURAL WASTES</topic><topic>Agronomy. Soil science and plant productions</topic><topic>BEETS</topic><topic>Biological and medical sciences</topic><topic>BIOMASA</topic><topic>BIOMASS</topic><topic>BIOMASSE</topic><topic>CARBON COMPOUNDS</topic><topic>CARBON DIOXIDE</topic><topic>CARBON OXIDES</topic><topic>CATALYTIC EFFECTS</topic><topic>CEREALS</topic><topic>CHALCOGENIDES</topic><topic>CHARS</topic><topic>CHEMICAL REACTIONS</topic><topic>DECHET AGRICOLE</topic><topic>DECOMPOSITION</topic><topic>DESECHOS AGRICOLAS</topic><topic>ELEMENTS</topic><topic>ENERGY SOURCES</topic><topic>FLUIDS</topic><topic>FOOD</topic><topic>FOSSIL FUELS</topic><topic>FUELS</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>GASES</topic><topic>GASIFICATION</topic><topic>General agronomy. Plant production</topic><topic>GRAMINEAE</topic><topic>LILIOPSIDA</topic><topic>MAGNOLIOPHYTA</topic><topic>MAGNOLIOPSIDA</topic><topic>METALS</topic><topic>ORGANIC MATTER</topic><topic>ORGANIC WASTES</topic><topic>OXIDES</topic><topic>OXYGEN COMPOUNDS</topic><topic>PEAT</topic><topic>PLANTS</topic><topic>POTATOES</topic><topic>PROCESAMIENTO</topic><topic>PYROLYSIS</topic><topic>PYROLYSIS PRODUCTS</topic><topic>RENEWABLE ENERGY SOURCES</topic><topic>SYNTHESIS GAS</topic><topic>THERMOCHEMICAL PROCESSES</topic><topic>TRAITEMENT</topic><topic>TUBERS</topic><topic>Use of agricultural and forest wastes. Biomass use, bioconversion</topic><topic>VEGETABLES</topic><topic>WASTES</topic><topic>WHEAT</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>DeGroot, William F</creatorcontrib><creatorcontrib>Kannan, M. Parambil</creatorcontrib><creatorcontrib>Richards, Geoffrey N</creatorcontrib><creatorcontrib>Theander, Olof</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of agricultural and food chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>DeGroot, William F</au><au>Kannan, M. Parambil</au><au>Richards, Geoffrey N</au><au>Theander, Olof</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Gasification of agricultural residues (biomass): influence of inorganic constituents</atitle><jtitle>Journal of agricultural and food chemistry</jtitle><addtitle>J. Agric. Food Chem</addtitle><date>1990-01-01</date><risdate>1990</risdate><volume>38</volume><issue>1</issue><spage>320</spage><epage>323</epage><pages>320-323</pages><issn>0021-8561</issn><eissn>1520-5118</eissn><coden>JAFCAU</coden><abstract>Four different biomass samples are included in this study, viz., sphagnum peat, wheat straw, sugar beet pulp, and potato pulp. They were chosen to represent a wide range of plant origin and inorganic content. This paper represents a preliminary investigation of an approach based on pyrolysis of biomass to produce volatile products and chars, followed by gasification of the chars. The particular interest lies in the investigation of the influence of the indigenous metal ions on the rate of gasification. Carbon dioxide has been used for the gasification, and the biomass was analyzed for nine metals, uronic acids (which are implicated in the binding of inorganic counterions), protein, and Klason lignin. The highest individual metal ion content was 13 964 ppm of potassium in potato pulp, and the gasification rates, under constant conditions, covered up to a 20-fold range, with char from potato pulp being the most readily gasified and char from peat the most resistant. The correlation of gasification rates with content of the major metal ions (alkali metals and alkaline earths) was poor. However, a high level of correlation was observed when wheat straw was omitted. It is speculate that the latter biomass may be anomalous with respect to the other three because of its high silica content</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/jf00091a070</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8561 |
| ispartof | Journal of agricultural and food chemistry, 1990-01, Vol.38 (1), p.320-323 |
| issn | 0021-8561 1520-5118 |
| language | eng |
| recordid | cdi_osti_scitechconnect_6552243 |
| source | American Chemical Society |
| subjects | 09 BIOMASS FUELS 090900 - Biomass Fuels- Processing- (1990-) AGRICULTURAL WASTES Agronomy. Soil science and plant productions BEETS Biological and medical sciences BIOMASA BIOMASS BIOMASSE CARBON COMPOUNDS CARBON DIOXIDE CARBON OXIDES CATALYTIC EFFECTS CEREALS CHALCOGENIDES CHARS CHEMICAL REACTIONS DECHET AGRICOLE DECOMPOSITION DESECHOS AGRICOLAS ELEMENTS ENERGY SOURCES FLUIDS FOOD FOSSIL FUELS FUELS Fundamental and applied biological sciences. Psychology GASES GASIFICATION General agronomy. Plant production GRAMINEAE LILIOPSIDA MAGNOLIOPHYTA MAGNOLIOPSIDA METALS ORGANIC MATTER ORGANIC WASTES OXIDES OXYGEN COMPOUNDS PEAT PLANTS POTATOES PROCESAMIENTO PYROLYSIS PYROLYSIS PRODUCTS RENEWABLE ENERGY SOURCES SYNTHESIS GAS THERMOCHEMICAL PROCESSES TRAITEMENT TUBERS Use of agricultural and forest wastes. Biomass use, bioconversion VEGETABLES WASTES WHEAT |
| title | Gasification of agricultural residues (biomass): influence of inorganic constituents |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-03T09%3A38%3A05IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Gasification%20of%20agricultural%20residues%20(biomass):%20influence%20of%20inorganic%20constituents&rft.jtitle=Journal%20of%20agricultural%20and%20food%20chemistry&rft.au=DeGroot,%20William%20F&rft.date=1990-01-01&rft.volume=38&rft.issue=1&rft.spage=320&rft.epage=323&rft.pages=320-323&rft.issn=0021-8561&rft.eissn=1520-5118&rft.coden=JAFCAU&rft_id=info:doi/10.1021/jf00091a070&rft_dat=%3Cacs_osti_%3Eb18170112%3C/acs_osti_%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a376t-2517c5804ba75aeb3ff18060a4186b6de9667a67ccd68d69296ea797073dc4963%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |