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Electronic structure and properties of rare earth and 3d transition metal compounds
Excitation energies of various electronic configurations in rare earth and 3d transition metal compounds are considered and related to the peculiarities of the observed electrical and optical properties. Intraionic excitations of 4f, 3d electrons to less localized nl states are shown to be equally i...
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Published in: | Journal of solid state chemistry 1994-03, Vol.109 (1), p.30-34 |
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container_end_page | 34 |
container_issue | 1 |
container_start_page | 30 |
container_title | Journal of solid state chemistry |
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creator | DAGYS, R BABONAS, G.-J |
description | Excitation energies of various electronic configurations in rare earth and 3d transition metal compounds are considered and related to the peculiarities of the observed electrical and optical properties. Intraionic excitations of 4f, 3d electrons to less localized nl states are shown to be equally important as interionic d-d or charge transfer transitions usually considered, and to be even more significant in compounds containing low valence metals. |
doi_str_mv | 10.1006/jssc.1994.1066 |
format | article |
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ispartof | Journal of solid state chemistry, 1994-03, Vol.109 (1), p.30-34 |
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language | eng |
recordid | cdi_osti_scitechconnect_6651945 |
source | Backfile Package - Materials Science [YMS]; Backfile Package - Physics General (Legacy) [YPA] |
subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties ELECTRICAL PROPERTIES Electron states ELECTRONIC STRUCTURE ENERGY LEVELS Exact sciences and technology EXCITED STATES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY OPTICAL PROPERTIES Other topics in electron states Other topics in electronic structure PHYSICAL PROPERTIES 400201 -- Chemical & Physicochemical Properties Physics RARE EARTH COMPOUNDS TRANSITION ELEMENT COMPOUNDS |
title | Electronic structure and properties of rare earth and 3d transition metal compounds |
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