A new antimony(III) molybdate with a layer structure: KSbMo sub 2 O sub 8

The crystal structure of KSbMo{sub 2}O{sub 8} was determined from single-crystal X-ray diffraction data. It crystallizes in the triclinic space group P{bar 1} with a = 5.015(2), b = 7.4216(6), c = 10.304(1) {angstrom}; {alpha} = 90.45(1), {beta} = 100.29(2), {gamma} = 107.79(1){degree}; V = 358.5 {a...

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Bibliographic Details
Published in:Journal of solid state chemistry 1990-06, Vol.86:2
Main Authors: Lii, K.H., Chueh, B.R., Wang, S.L.
Format: Article
Language:English
Subjects:
ANTIMONY COMPOUNDS
COHERENT SCATTERING
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DATA
DATA ANALYSIS
DIFFRACTION
EXPERIMENTAL DATA
INFORMATION
MATERIALS SCIENCE
MEASURING INSTRUMENTS
MEASURING METHODS
MOLYBDATES
MOLYBDENUM COMPOUNDS
NUMERICAL DATA
OXYGEN COMPOUNDS
REFRACTORY METAL COMPOUNDS
SCATTERING
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS 360202 > Ceramics, Cermets, & Refractories-- Structure & Phase Studies
TRICLINIC LATTICES
X-RAY DIFFRACTION
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Summary:The crystal structure of KSbMo{sub 2}O{sub 8} was determined from single-crystal X-ray diffraction data. It crystallizes in the triclinic space group P{bar 1} with a = 5.015(2), b = 7.4216(6), c = 10.304(1) {angstrom}; {alpha} = 90.45(1), {beta} = 100.29(2), {gamma} = 107.79(1){degree}; V = 358.5 {angstrom}{sup 3}, Z = 2, R = 0.028, R{sub w} = 0.038 for 1,590 unique reflections with I > 2.5 {sigma}(I). The structure contains layers of antimony molybdate with the potassium polyhedra and consists of two types of chains parallel to the a-axis.
ISSN:0022-4596
1095-726X
DOI:10.1016/0022-4596(90)90134-J