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Theoretical study of nonresonant sup 3 He sup + + sup 4 He r reversible sup 3 He+ sup 4 He sup + charge transfer in the threshold region

A quantum-mechanical calculation of charge-transfer cross sections for the forward (endothermic) and backward (exothermic) collision processes {sup 3}He{sup +}+{sup 4}He {r reversible} {sup 3}He+{sup 4}He{sup +} in the threshold energy region has been carried out by using a two-state close-coupling...

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Bibliographic Details
Published in:Physical review. A, Atomic, molecular, and optical physics Atomic, molecular, and optical physics, 1992-10, Vol.46:7
Main Authors: Dutta, C.M., Lane, N.F., Kimura, M.
Format: Article
Language:English
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Summary:A quantum-mechanical calculation of charge-transfer cross sections for the forward (endothermic) and backward (exothermic) collision processes {sup 3}He{sup +}+{sup 4}He {r reversible} {sup 3}He+{sup 4}He{sup +} in the threshold energy region has been carried out by using a two-state close-coupling treatment where the charge-transfer energy defect, approximately 1.3 meV, is the isotopic term difference between the {sup 3}He and {sup 4}He binding energies. The cross sections show numerous shape and orbiting resonances, which can be labeled with predissociation rotational and vibrational quantum numbers. From these cross sections, the forward and backward rate coefficients have been calculated. The present results, particularly the ratio of forward and backward rate coefficients, agree well with measurements of Schauer, Jefferts, and Dunn (Phys. Rev. A 42, 5332 (1990)).
ISSN:1050-2947
1094-1622
DOI:10.1103/PhysRevA.46.3889