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Synthesis and electronic characterization of discrete buckminsterfulleride salts. C[sub 60][sup 2[minus]] and C[sub 60][sup 3[minus]]

The synthesis and magnetic characterization of discrete fulleride salts is leading to interesting new insight into the rather complex electronic structures that result from sequential filling of the t[sub lu] LUMO of C[sub 60]. Hund's rule is not obeyed in either C[sub 60][sup 2[minus]] or C[su...

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Published in:	Journal of the American Chemical Society 1993-11, Vol.115:23
Main Authors:	Bhyrappa, P., Stinchcombe, J., Reed, C.A., Paul, P., Boyd, P.D.W.
Format:	Article
Language:	English
Subjects:	400102 - Chemical & Spectral Procedures 400201 - Chemical & Physicochemical Properties CARBON CHARGED PARTICLES ELECTRON SPIN RESONANCE ELECTRONIC STRUCTURE ELEMENTS FULLERENES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONS MAGNETIC RESONANCE NONMETALS NUCLEAR MAGNETIC RESONANCE RESONANCE SALTS SYNTHESIS
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container_title	Journal of the American Chemical Society
container_volume	115:23
creator	Bhyrappa, P. Stinchcombe, J. Reed, C.A. Paul, P. Boyd, P.D.W.
description	The synthesis and magnetic characterization of discrete fulleride salts is leading to interesting new insight into the rather complex electronic structures that result from sequential filling of the t[sub lu] LUMO of C[sub 60]. Hund's rule is not obeyed in either C[sub 60][sup 2[minus]] or C[sub 60][sup 3[minus]] because of the density of low-lying excited states which remain to be described in detail. The preference for a consistent A/E splitting of the T[sub lu] level upon filling with one, two, or three electrons is notable, particularly because in each case there are elements of the configuration that are counter-intuitive with respect to the Jahn-Teller theorem. 15 refs., 2 figs.
doi_str_mv	10.1021/ja00076a074
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subjects	400102 - Chemical & Spectral Procedures 400201 - Chemical & Physicochemical Properties CARBON CHARGED PARTICLES ELECTRON SPIN RESONANCE ELECTRONIC STRUCTURE ELEMENTS FULLERENES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONS MAGNETIC RESONANCE NONMETALS NUCLEAR MAGNETIC RESONANCE RESONANCE SALTS SYNTHESIS
title	Synthesis and electronic characterization of discrete buckminsterfulleride salts. C[sub 60][sup 2[minus]] and C[sub 60][sup 3[minus]]
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