Partial oxidation of methane by nitrous oxide

Partial oxidation of methane by nitrous oxide has been studied behind reflected shock waves in a single-pulse shock tube over the temperature range of 1,400-1,940 K, at a pressure of 15 atm, and with uniform gas residence time of 0.4 ms. Mixtures of N{sub 2}O and CH{sub 4}, each of mole fraction 0.0...

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Bibliographic Details
Published in:Energy & fuels 1990-05, Vol.4 (3), p.285-290
Main Authors: Mackie, John C, Hart, Malcolm G
Format: Article
Language:English
Subjects:
09 BIOMASS FUELS
091000 - Biomass Fuels- Properties & Composition- (1990-)
400800 - Combustion, Pyrolysis, & High-Temperature Chemistry
ALKANES
Applied sciences
CHALCOGENIDES
CHEMICAL REACTIONS
DATA
DATA ANALYSIS
Energy
Exact sciences and technology
EXPERIMENTAL DATA
Fuel processing. Carbochemistry and petrochemistry
Fuels
Gas processing
HYDROCARBONS
INFORMATION
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
MEASURING INSTRUMENTS
MEASURING METHODS
MEDIUM PRESSURE
METHANE
NITROGEN COMPOUNDS
NITROGEN OXIDES
NITROUS OXIDE
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PARTIAL OXIDATION PROCESSES
SHOCK WAVES
THERMOCHEMICAL PROCESSES
VERY HIGH TEMPERATURE
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Summary:Partial oxidation of methane by nitrous oxide has been studied behind reflected shock waves in a single-pulse shock tube over the temperature range of 1,400-1,940 K, at a pressure of 15 atm, and with uniform gas residence time of 0.4 ms. Mixtures of N{sub 2}O and CH{sub 4}, each of mole fraction 0.01 in Ar, commenced decomposition at temperatures above 1,400 K. Ethane and ethylene are the principal carbon-containing products of partial oxidation below 1,580 K.
ISSN:0887-0624
1520-5029
DOI:10.1021/ef00021a012