Structure, reactivity, and energetics of covalently bound carbon cluster ions, C sub 5 sup + to C sub 11 sup + : Experiment and theory

Laser ablation from a rotating, translating graphite rod is used to create a broad distribution of internally energized carbon cluster ions C{sub n}{sup +}. These energized clusters are accelerated, size selected by a magnet, and allowed to undergo unimolecular decay in a field-free region. The deca...

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Bibliographic Details
Published in:Journal of physical chemistry (1952) 1989-08, Vol.93:16
Main Authors: Radi, P.P., Rincon, M.E., Hsu, M.T., Brodbelt-Lustig, J., Kemper, P., Bowers, M.T.
Format: Article
Language:English
Subjects:
360603 - Materials- Properties
400000 - Chemistry
400201 - Chemical & Physicochemical Properties
400800 - Combustion, Pyrolysis, & High-Temperature Chemistry
CARBON
CATALYSTS
DATA
DATA ANALYSIS
ELEMENTS
ENERGY LEVELS
EXPERIMENTAL DATA
INFORMATION
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
MATERIALS SCIENCE
MEASURING INSTRUMENTS
MEASURING METHODS
NONMETALS
NUMERICAL DATA
SOLID CLUSTERS
STRUCTURAL CHEMICAL ANALYSIS
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Summary:Laser ablation from a rotating, translating graphite rod is used to create a broad distribution of internally energized carbon cluster ions C{sub n}{sup +}. These energized clusters are accelerated, size selected by a magnet, and allowed to undergo unimolecular decay in a field-free region. The decay products are mass and energy analyzed by a high-resolution electrostatic analyzer. In this work they are interested in clusters in the range 5 {
ISSN:0022-3654
1541-5740
DOI:10.1021/j100353a045