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Simulation of a Four-Bed Pressure Swing Adsorption Process for Oxygen Enrichment

Pressure swing adsorption (PSA) is a cyclic process for gas purification and separation. More and more commercial separation processes employing PSA technology have been developed since the first patent of a PSA process in the US was described. This separation technology needs lower energy and is le...

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Bibliographic Details
Published in:Industrial & engineering chemistry research 1994-05, Vol.33 (5), p.1250-1258
Main Authors: Chou, C, Huang, Wen-Chun
Format: Article
Language:English
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Summary:Pressure swing adsorption (PSA) is a cyclic process for gas purification and separation. More and more commercial separation processes employing PSA technology have been developed since the first patent of a PSA process in the US was described. This separation technology needs lower energy and is less costly than the conventional separation processes like absorption and distillation, and it can provide a very efficient and flexible means of gas separation. Dynamic simulation with the valve equation approach of a four-bed pressure swing adsorption (PSA) process for oxygen enrichment over zeolite 5A was performed. Product pressurization, feed pressurization, production, blowdown, purge, and pressure equalization are included in this process. The numerical results were compared to the experimental results of Chiang et al. (1994) and gave reasonable agreements. The effects of production rate and purge rate on the purity and recovery were also explored by simulation. When breakthrough did not occur for the depressurizing bed during the pressure equalization step, operation at the minimum purge rate gave a relatively high recovery for producing a product of purity more than 95% oxygen. When breakthrough occurred, the theoretical results show that, for a fixed production rate, there is a purge rate giving the maximum recovery and a different purge rate giving the highest purity.
ISSN:0888-5885
1520-5045
DOI:10.1021/ie00029a022