Tracer diffusion study of CuCl

Diffusion coefficients for Cu − diffusion in γ- and β-phase CuCl have been measured with an in situ tracer diffusion technique. The diffusion coefficients were measured at five temperatures in the γ-phase and at two temperatures in the β-phase. The diffusion in the γ-phase was shown to follow an Arr...

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Bibliographic Details
Published in:Journal of solid state chemistry 1992-06, Vol.98 (2), p.263-268
Main Authors: Jørgensen, Jens-Erik, Johansson, J.X.M.Z., Sköld, K.
Format: Article
Language:English
Subjects:
360606 - Other Materials- Physical Properties- (1992-)
400201 - Chemical & Physicochemical Properties
ACTIVATION ANALYSIS
ACTIVATION ENERGY
ARRHENIUS EQUATION
CHARGED PARTICLES
CHEMICAL ANALYSIS
Chemical interdiffusion
diffusion barriers
CHLORIDES
CHLORINE COMPOUNDS
Condensed matter: structure, mechanical and thermal properties
COPPER
COPPER CHLORIDES
COPPER COMPOUNDS
COPPER HALIDES
COPPER IONS
DIFFUSION
Diffusion in solids
ELEMENTS
ENERGY
EQUATIONS
Exact sciences and technology
HALIDES
HALOGEN COMPOUNDS
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
IONS
MATERIALS SCIENCE
MATHEMATICAL MODELS
METALS
NEUTRON ACTIVATION ANALYSIS
PERMEABILITY
PHASE STUDIES
Physics
TEMPERATURE DEPENDENCE
TEMPERATURE RANGE
TEMPERATURE RANGE 0400-1000 K
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
Transport properties of condensed matter (nonelectronic)
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Summary:Diffusion coefficients for Cu − diffusion in γ- and β-phase CuCl have been measured with an in situ tracer diffusion technique. The diffusion coefficients were measured at five temperatures in the γ-phase and at two temperatures in the β-phase. The diffusion in the γ-phase was shown to follow an Arrhenius law with an activation energy of 1.4(1) eV.
ISSN:0022-4596
1095-726X
DOI:10.1016/S0022-4596(05)80234-8