Influence of ceria on the NOx storage/reduction behavior of lean NOx trap catalysts

The effect of La2O3-stabilized ceria incorporation on the functioning of fully formulated lean NOx trap catalysts was investigated. Monolithic catalysts were prepared, corresponding to loadings of 0, 50 and 100 g CeO2/L, together with a catalyst containing 100 g/L of ceria-zirconia (Ce0.7Zr0.3O2). L...

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Bibliographic Details
Published in:Catalysis today 2008-07, Vol.136 (1-2), p.146-155
Main Authors: YAYING JI, CHOI, Jae-Soon, TOOPS, Todd J, CROCKER, Mark, NASERI, Mojghan
Format: Article
Language:English
Subjects:
ADVANCED PROPULSION SYSTEMS
AIR POLLUTION ABATEMENT
BARIUM OXIDES
Catalysis
CATALYSTS
CATALYTIC EFFECTS
CERIUM OXIDES
Chemistry
DIESEL ENGINES
ENVIRONMENTAL SCIENCES
Exact sciences and technology
EXHAUST GASES
General and physical chemistry
NITROGEN OXIDES
PLATINUM
REDUCTION
RHODIUM
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
ZIRCONIUM OXIDES
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Summary:The effect of La2O3-stabilized ceria incorporation on the functioning of fully formulated lean NOx trap catalysts was investigated. Monolithic catalysts were prepared, corresponding to loadings of 0, 50 and 100 g CeO2/L, together with a catalyst containing 100 g/L of ceria-zirconia (Ce0.7Zr0.3O2). Loadings of the other main components (Pt, Rh and BaO) were held constant. Catalyst evaluation was performed on a bench flow reactor under simulated diesel exhaust conditions, employing NOx storage/reduction cycles. NOx storage efficiency in the temperature range 150-350 C was observed to increase with ceria loading, resulting in higher NOx conversion levels. At 150 C, high rich phase NOx slip was observed for all of the catalysts, resulting from an imbalance in the rates of nitrate decomposition and NOx reduction. Optimal NOx conversion was obtained in the range 250-350 C for all the catalysts, while at 450 C high rich phase NOx slip from the most highly loaded ceria-containing catalyst resulted in lower NOx conversion than for the ceria-free formulation. N2O was the major NOx reduction product at 150 C over all of the catalysts, although low NOx conversion levels limited the N2O yield. At higher temperatures N2 was the main product of NOx reduction, although NH3 formation was also observed. Selectivity to NH3 decreased with increasing ceria loading, indicating that NH3 is consumed by reaction with stored oxygen in the rear of the catalyst.
ISSN:0920-5861
1873-4308
DOI:10.1016/j.cattod.2007.11.059