Solvent mediated assembly of nanoparticles confined in mesoporous alumina

The controlled self-assembly of thiol stabilized gold nanocrystals in a mediating solvent and confined within mesoporous alumina was probed in situ with small angle x-ray scattering. The evolution of the self-assembly process was controlled reversibly via regulated changes in the amount of solvent c...

Full description

Saved in:
Bibliographic Details
Published in:Physical review. B, Condensed matter and materials physics Condensed matter and materials physics, 2006-03, Vol.73 (12), Article 125412
Main Authors: Alvine, Kyle J., Pontoni, Diego, Shpyrko, Oleg G., Pershan, Peter S., Cookson, David J., Shin, Kyusoon, Russell, Thomas P., Brunnbauer, Markus, Stellacci, Francesco, Gang, Oleg
Format: Article
Language:English
Subjects:
ABSORPTION
ALUMINIUM OXIDES
DESORPTION
GOLD
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
NANOSCIENCE AND NANOTECHNOLOGY
NANOSTRUCTURES
POROUS MATERIALS
SOLVENTS
THIOLS
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c317t-8f5deef4431bd80841a9a7016834b24ac09a0e870e8f620357597bc4860e51073
cites cdi_FETCH-LOGICAL-c317t-8f5deef4431bd80841a9a7016834b24ac09a0e870e8f620357597bc4860e51073
container_end_page
container_issue 12
container_start_page
container_title Physical review. B, Condensed matter and materials physics
container_volume 73
creator Alvine, Kyle J.
Pontoni, Diego
Shpyrko, Oleg G.
Pershan, Peter S.
Cookson, David J.
Shin, Kyusoon
Russell, Thomas P.
Brunnbauer, Markus
Stellacci, Francesco
Gang, Oleg
description The controlled self-assembly of thiol stabilized gold nanocrystals in a mediating solvent and confined within mesoporous alumina was probed in situ with small angle x-ray scattering. The evolution of the self-assembly process was controlled reversibly via regulated changes in the amount of solvent condensed from an undersaturated vapor. Analysis indicated that the nanoparticles self-assembled into cylindrical monolayers within the porous template. Nanoparticle nearest-neighbor separation within the monolayer increased and the ordering decreased with the controlled addition of solvent. The process was reversible with the removal of solvent. Isotropic clusters of nanoparticles were also observed to form temporarily during desorption of the liquid solvent and disappeared upon complete removal of liquid. Measurements of the absorption and desorption of the solvent showed strong hysteresis upon thermal cycling. In addition, the capillary filling transition for the solvent in the nanoparticle-doped pores was shifted to larger chemical potential, relative to the liquid/vapor coexistence, by a factor of 4 as compared to the expected value for the same system without nanoparticles.
doi_str_mv 10.1103/PhysRevB.73.125412
format article
fullrecord <record><control><sourceid>crossref_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_953448</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1103_PhysRevB_73_125412</sourcerecordid><originalsourceid>FETCH-LOGICAL-c317t-8f5deef4431bd80841a9a7016834b24ac09a0e870e8f620357597bc4860e51073</originalsourceid><addsrcrecordid>eNo1kNtKAzEURYMoWKs_4NP4ATOek0uTedTipVBQvIBvIZPJ0MhMUiZpoX_vSPXhsM_DYrNZhFwjVIjAbl83h_Tm9veVZBVSwZGekBkKASVl4ut0-qFWJSDFc3KR0jcA8prTGVm9x37vQi4G13qTXVuYlNzQ9IcidkUwIW7NmL3tXSpsDJ0PE-LDhKe4jWPcpcL0u8EHc0nOOtMnd_WXc_L5-PCxfC7XL0-r5d26tAxlLlUnWuc6zhk2rQLF0dRGAi4U4w3lxkJtwCk5XbegwIQUtWwsVwtwAkGyObk59saUvU7WZ2c307TgbNa1YJyriaFHxo4xpdF1ejv6wYwHjaB_hel_YVoyfRTGfgAOy2B0</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Solvent mediated assembly of nanoparticles confined in mesoporous alumina</title><source>American Physical Society:Jisc Collections:APS Read and Publish 2023-2025 (reading list)</source><creator>Alvine, Kyle J. ; Pontoni, Diego ; Shpyrko, Oleg G. ; Pershan, Peter S. ; Cookson, David J. ; Shin, Kyusoon ; Russell, Thomas P. ; Brunnbauer, Markus ; Stellacci, Francesco ; Gang, Oleg</creator><creatorcontrib>Alvine, Kyle J. ; Pontoni, Diego ; Shpyrko, Oleg G. ; Pershan, Peter S. ; Cookson, David J. ; Shin, Kyusoon ; Russell, Thomas P. ; Brunnbauer, Markus ; Stellacci, Francesco ; Gang, Oleg ; Argonne National Lab. (ANL), Argonne, IL (United States)</creatorcontrib><description>The controlled self-assembly of thiol stabilized gold nanocrystals in a mediating solvent and confined within mesoporous alumina was probed in situ with small angle x-ray scattering. The evolution of the self-assembly process was controlled reversibly via regulated changes in the amount of solvent condensed from an undersaturated vapor. Analysis indicated that the nanoparticles self-assembled into cylindrical monolayers within the porous template. Nanoparticle nearest-neighbor separation within the monolayer increased and the ordering decreased with the controlled addition of solvent. The process was reversible with the removal of solvent. Isotropic clusters of nanoparticles were also observed to form temporarily during desorption of the liquid solvent and disappeared upon complete removal of liquid. Measurements of the absorption and desorption of the solvent showed strong hysteresis upon thermal cycling. In addition, the capillary filling transition for the solvent in the nanoparticle-doped pores was shifted to larger chemical potential, relative to the liquid/vapor coexistence, by a factor of 4 as compared to the expected value for the same system without nanoparticles.</description><identifier>ISSN: 1098-0121</identifier><identifier>EISSN: 1550-235X</identifier><identifier>DOI: 10.1103/PhysRevB.73.125412</identifier><language>eng</language><publisher>United States</publisher><subject>ABSORPTION ; ALUMINIUM OXIDES ; DESORPTION ; GOLD ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; NANOSCIENCE AND NANOTECHNOLOGY ; NANOSTRUCTURES ; POROUS MATERIALS ; SOLVENTS ; THIOLS</subject><ispartof>Physical review. B, Condensed matter and materials physics, 2006-03, Vol.73 (12), Article 125412</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c317t-8f5deef4431bd80841a9a7016834b24ac09a0e870e8f620357597bc4860e51073</citedby><cites>FETCH-LOGICAL-c317t-8f5deef4431bd80841a9a7016834b24ac09a0e870e8f620357597bc4860e51073</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/953448$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Alvine, Kyle J.</creatorcontrib><creatorcontrib>Pontoni, Diego</creatorcontrib><creatorcontrib>Shpyrko, Oleg G.</creatorcontrib><creatorcontrib>Pershan, Peter S.</creatorcontrib><creatorcontrib>Cookson, David J.</creatorcontrib><creatorcontrib>Shin, Kyusoon</creatorcontrib><creatorcontrib>Russell, Thomas P.</creatorcontrib><creatorcontrib>Brunnbauer, Markus</creatorcontrib><creatorcontrib>Stellacci, Francesco</creatorcontrib><creatorcontrib>Gang, Oleg</creatorcontrib><creatorcontrib>Argonne National Lab. (ANL), Argonne, IL (United States)</creatorcontrib><title>Solvent mediated assembly of nanoparticles confined in mesoporous alumina</title><title>Physical review. B, Condensed matter and materials physics</title><description>The controlled self-assembly of thiol stabilized gold nanocrystals in a mediating solvent and confined within mesoporous alumina was probed in situ with small angle x-ray scattering. The evolution of the self-assembly process was controlled reversibly via regulated changes in the amount of solvent condensed from an undersaturated vapor. Analysis indicated that the nanoparticles self-assembled into cylindrical monolayers within the porous template. Nanoparticle nearest-neighbor separation within the monolayer increased and the ordering decreased with the controlled addition of solvent. The process was reversible with the removal of solvent. Isotropic clusters of nanoparticles were also observed to form temporarily during desorption of the liquid solvent and disappeared upon complete removal of liquid. Measurements of the absorption and desorption of the solvent showed strong hysteresis upon thermal cycling. In addition, the capillary filling transition for the solvent in the nanoparticle-doped pores was shifted to larger chemical potential, relative to the liquid/vapor coexistence, by a factor of 4 as compared to the expected value for the same system without nanoparticles.</description><subject>ABSORPTION</subject><subject>ALUMINIUM OXIDES</subject><subject>DESORPTION</subject><subject>GOLD</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>NANOSCIENCE AND NANOTECHNOLOGY</subject><subject>NANOSTRUCTURES</subject><subject>POROUS MATERIALS</subject><subject>SOLVENTS</subject><subject>THIOLS</subject><issn>1098-0121</issn><issn>1550-235X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNo1kNtKAzEURYMoWKs_4NP4ATOek0uTedTipVBQvIBvIZPJ0MhMUiZpoX_vSPXhsM_DYrNZhFwjVIjAbl83h_Tm9veVZBVSwZGekBkKASVl4ut0-qFWJSDFc3KR0jcA8prTGVm9x37vQi4G13qTXVuYlNzQ9IcidkUwIW7NmL3tXSpsDJ0PE-LDhKe4jWPcpcL0u8EHc0nOOtMnd_WXc_L5-PCxfC7XL0-r5d26tAxlLlUnWuc6zhk2rQLF0dRGAi4U4w3lxkJtwCk5XbegwIQUtWwsVwtwAkGyObk59saUvU7WZ2c307TgbNa1YJyriaFHxo4xpdF1ejv6wYwHjaB_hel_YVoyfRTGfgAOy2B0</recordid><startdate>20060301</startdate><enddate>20060301</enddate><creator>Alvine, Kyle J.</creator><creator>Pontoni, Diego</creator><creator>Shpyrko, Oleg G.</creator><creator>Pershan, Peter S.</creator><creator>Cookson, David J.</creator><creator>Shin, Kyusoon</creator><creator>Russell, Thomas P.</creator><creator>Brunnbauer, Markus</creator><creator>Stellacci, Francesco</creator><creator>Gang, Oleg</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>20060301</creationdate><title>Solvent mediated assembly of nanoparticles confined in mesoporous alumina</title><author>Alvine, Kyle J. ; Pontoni, Diego ; Shpyrko, Oleg G. ; Pershan, Peter S. ; Cookson, David J. ; Shin, Kyusoon ; Russell, Thomas P. ; Brunnbauer, Markus ; Stellacci, Francesco ; Gang, Oleg</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c317t-8f5deef4431bd80841a9a7016834b24ac09a0e870e8f620357597bc4860e51073</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>ABSORPTION</topic><topic>ALUMINIUM OXIDES</topic><topic>DESORPTION</topic><topic>GOLD</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>NANOSCIENCE AND NANOTECHNOLOGY</topic><topic>NANOSTRUCTURES</topic><topic>POROUS MATERIALS</topic><topic>SOLVENTS</topic><topic>THIOLS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Alvine, Kyle J.</creatorcontrib><creatorcontrib>Pontoni, Diego</creatorcontrib><creatorcontrib>Shpyrko, Oleg G.</creatorcontrib><creatorcontrib>Pershan, Peter S.</creatorcontrib><creatorcontrib>Cookson, David J.</creatorcontrib><creatorcontrib>Shin, Kyusoon</creatorcontrib><creatorcontrib>Russell, Thomas P.</creatorcontrib><creatorcontrib>Brunnbauer, Markus</creatorcontrib><creatorcontrib>Stellacci, Francesco</creatorcontrib><creatorcontrib>Gang, Oleg</creatorcontrib><creatorcontrib>Argonne National Lab. (ANL), Argonne, IL (United States)</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Physical review. B, Condensed matter and materials physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Alvine, Kyle J.</au><au>Pontoni, Diego</au><au>Shpyrko, Oleg G.</au><au>Pershan, Peter S.</au><au>Cookson, David J.</au><au>Shin, Kyusoon</au><au>Russell, Thomas P.</au><au>Brunnbauer, Markus</au><au>Stellacci, Francesco</au><au>Gang, Oleg</au><aucorp>Argonne National Lab. (ANL), Argonne, IL (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solvent mediated assembly of nanoparticles confined in mesoporous alumina</atitle><jtitle>Physical review. B, Condensed matter and materials physics</jtitle><date>2006-03-01</date><risdate>2006</risdate><volume>73</volume><issue>12</issue><artnum>125412</artnum><issn>1098-0121</issn><eissn>1550-235X</eissn><abstract>The controlled self-assembly of thiol stabilized gold nanocrystals in a mediating solvent and confined within mesoporous alumina was probed in situ with small angle x-ray scattering. The evolution of the self-assembly process was controlled reversibly via regulated changes in the amount of solvent condensed from an undersaturated vapor. Analysis indicated that the nanoparticles self-assembled into cylindrical monolayers within the porous template. Nanoparticle nearest-neighbor separation within the monolayer increased and the ordering decreased with the controlled addition of solvent. The process was reversible with the removal of solvent. Isotropic clusters of nanoparticles were also observed to form temporarily during desorption of the liquid solvent and disappeared upon complete removal of liquid. Measurements of the absorption and desorption of the solvent showed strong hysteresis upon thermal cycling. In addition, the capillary filling transition for the solvent in the nanoparticle-doped pores was shifted to larger chemical potential, relative to the liquid/vapor coexistence, by a factor of 4 as compared to the expected value for the same system without nanoparticles.</abstract><cop>United States</cop><doi>10.1103/PhysRevB.73.125412</doi><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1098-0121
ispartof Physical review. B, Condensed matter and materials physics, 2006-03, Vol.73 (12), Article 125412
issn 1098-0121
1550-235X
language eng
recordid cdi_osti_scitechconnect_953448
source American Physical Society:Jisc Collections:APS Read and Publish 2023-2025 (reading list)
subjects ABSORPTION
ALUMINIUM OXIDES
DESORPTION
GOLD
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
NANOSCIENCE AND NANOTECHNOLOGY
NANOSTRUCTURES
POROUS MATERIALS
SOLVENTS
THIOLS
title Solvent mediated assembly of nanoparticles confined in mesoporous alumina
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T02%3A18%3A49IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Solvent%20mediated%20assembly%20of%20nanoparticles%20confined%20in%20mesoporous%20alumina&rft.jtitle=Physical%20review.%20B,%20Condensed%20matter%20and%20materials%20physics&rft.au=Alvine,%20Kyle%20J.&rft.aucorp=Argonne%20National%20Lab.%20(ANL),%20Argonne,%20IL%20(United%20States)&rft.date=2006-03-01&rft.volume=73&rft.issue=12&rft.artnum=125412&rft.issn=1098-0121&rft.eissn=1550-235X&rft_id=info:doi/10.1103/PhysRevB.73.125412&rft_dat=%3Ccrossref_osti_%3E10_1103_PhysRevB_73_125412%3C/crossref_osti_%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c317t-8f5deef4431bd80841a9a7016834b24ac09a0e870e8f620357597bc4860e51073%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true