Evidence of Oxygen Intercalation and Mobility at Room Temperature in Oxides:  An Electrochemical Quartz Microbalance Study of Intercalation in La2CuO4

This paper offers direct evidence for the electrochemical intercalation of oxygen in an oxide with the K2NiF4 structure, namely, La2CuO4, at room temperature. Organic solvents, as well as water, allow that reaction to occur. The charge-to-mass ratio evaluated from a comparison with fluoride intercal...

Full description

Saved in:
Bibliographic Details
Published in:Chemistry of materials 2001-06, Vol.13 (6), p.2118-2126
Main Authors: Casañ-Pastor, N, Zinck, C, Michel, C. R, Tejada-Rosales, E. M, Torres-Gómez, G
Format: Article
Language:English
Subjects:
Chemistry
Electrochemistry
Electrodes: preparations and properties
Exact sciences and technology
General and physical chemistry
Other electrodes
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 2126
container_issue 6
container_start_page 2118
container_title Chemistry of materials
container_volume 13
creator Casañ-Pastor, N
Zinck, C
Michel, C. R
Tejada-Rosales, E. M
Torres-Gómez, G
description This paper offers direct evidence for the electrochemical intercalation of oxygen in an oxide with the K2NiF4 structure, namely, La2CuO4, at room temperature. Organic solvents, as well as water, allow that reaction to occur. The charge-to-mass ratio evaluated from a comparison with fluoride intercalation implies that either OH- or Oδ- species are being intercalated. Comparison with previous work seems to favor the latter. If an oxygen with lower charge is moving, that could indeed explain why oxygen conductivity can be observed at such low temperatures.
doi_str_mv 10.1021/cm001404t
format article
fullrecord <record><control><sourceid>acs_pasca</sourceid><recordid>TN_cdi_pascalfrancis_primary_1082554</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>b600275325</sourcerecordid><originalsourceid>FETCH-LOGICAL-a250t-684ef7b2d9acd4bbc1acb9f3a41bcde22a1225a393efe8a8e3de97381bb9bb1b3</originalsourceid><addsrcrecordid>eNpVkUtOwzAQhi0EEuWx4AZewDJgO06TsIOqPFuVR1lbY2cChiapHAdRVmy5AefjJLgqQmI1i_nm-2c0hOxxdsiZ4EemYoxLJv0a6fFEsChhTKyTHsvyNJJp0t8kW237HKCAZz3yNXy1BdYGaVPSydviEWt6WXt0BmbgbVNTqAs6brSdWb-g4Old01R0itUcHfjOIbV1GAyS9vj745Oe1HQ4Q-NdY56wskFDbztw_p2OrXGNDtpl2r3visUy839YcI1ADLqJ3CEbJcxa3P2t2-ThbDgdXESjyfnl4GQUgUiYj_qZxDLVosjBFFJrw8HovIxBcm0KFAK4EAnEeYwlZpBhXGCexhnXOtea63ib7K-8c2jDGqUL69lWzZ2twC0UZ5lIEhmwaIXZ1uPbXxvci-qncZqo6c29yq9Ox9djmatB4A9WPJhWPTedq8MRwaaWX1J_X4p_ALoEh7U</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Evidence of Oxygen Intercalation and Mobility at Room Temperature in Oxides:  An Electrochemical Quartz Microbalance Study of Intercalation in La2CuO4</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read &amp; Publish Agreement 2022-2024 (Reading list)</source><creator>Casañ-Pastor, N ; Zinck, C ; Michel, C. R ; Tejada-Rosales, E. M ; Torres-Gómez, G</creator><creatorcontrib>Casañ-Pastor, N ; Zinck, C ; Michel, C. R ; Tejada-Rosales, E. M ; Torres-Gómez, G</creatorcontrib><description>This paper offers direct evidence for the electrochemical intercalation of oxygen in an oxide with the K2NiF4 structure, namely, La2CuO4, at room temperature. Organic solvents, as well as water, allow that reaction to occur. The charge-to-mass ratio evaluated from a comparison with fluoride intercalation implies that either OH- or Oδ- species are being intercalated. Comparison with previous work seems to favor the latter. If an oxygen with lower charge is moving, that could indeed explain why oxygen conductivity can be observed at such low temperatures.</description><identifier>ISSN: 0897-4756</identifier><identifier>EISSN: 1520-5002</identifier><identifier>DOI: 10.1021/cm001404t</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Electrochemistry ; Electrodes: preparations and properties ; Exact sciences and technology ; General and physical chemistry ; Other electrodes</subject><ispartof>Chemistry of materials, 2001-06, Vol.13 (6), p.2118-2126</ispartof><rights>Copyright © 2001 American Chemical Society</rights><rights>2001 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=1082554$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Casañ-Pastor, N</creatorcontrib><creatorcontrib>Zinck, C</creatorcontrib><creatorcontrib>Michel, C. R</creatorcontrib><creatorcontrib>Tejada-Rosales, E. M</creatorcontrib><creatorcontrib>Torres-Gómez, G</creatorcontrib><title>Evidence of Oxygen Intercalation and Mobility at Room Temperature in Oxides:  An Electrochemical Quartz Microbalance Study of Intercalation in La2CuO4</title><title>Chemistry of materials</title><addtitle>Chem. Mater</addtitle><description>This paper offers direct evidence for the electrochemical intercalation of oxygen in an oxide with the K2NiF4 structure, namely, La2CuO4, at room temperature. Organic solvents, as well as water, allow that reaction to occur. The charge-to-mass ratio evaluated from a comparison with fluoride intercalation implies that either OH- or Oδ- species are being intercalated. Comparison with previous work seems to favor the latter. If an oxygen with lower charge is moving, that could indeed explain why oxygen conductivity can be observed at such low temperatures.</description><subject>Chemistry</subject><subject>Electrochemistry</subject><subject>Electrodes: preparations and properties</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Other electrodes</subject><issn>0897-4756</issn><issn>1520-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNpVkUtOwzAQhi0EEuWx4AZewDJgO06TsIOqPFuVR1lbY2cChiapHAdRVmy5AefjJLgqQmI1i_nm-2c0hOxxdsiZ4EemYoxLJv0a6fFEsChhTKyTHsvyNJJp0t8kW237HKCAZz3yNXy1BdYGaVPSydviEWt6WXt0BmbgbVNTqAs6brSdWb-g4Old01R0itUcHfjOIbV1GAyS9vj745Oe1HQ4Q-NdY56wskFDbztw_p2OrXGNDtpl2r3visUy839YcI1ADLqJ3CEbJcxa3P2t2-ThbDgdXESjyfnl4GQUgUiYj_qZxDLVosjBFFJrw8HovIxBcm0KFAK4EAnEeYwlZpBhXGCexhnXOtea63ib7K-8c2jDGqUL69lWzZ2twC0UZ5lIEhmwaIXZ1uPbXxvci-qncZqo6c29yq9Ox9djmatB4A9WPJhWPTedq8MRwaaWX1J_X4p_ALoEh7U</recordid><startdate>20010618</startdate><enddate>20010618</enddate><creator>Casañ-Pastor, N</creator><creator>Zinck, C</creator><creator>Michel, C. R</creator><creator>Tejada-Rosales, E. M</creator><creator>Torres-Gómez, G</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope></search><sort><creationdate>20010618</creationdate><title>Evidence of Oxygen Intercalation and Mobility at Room Temperature in Oxides:  An Electrochemical Quartz Microbalance Study of Intercalation in La2CuO4</title><author>Casañ-Pastor, N ; Zinck, C ; Michel, C. R ; Tejada-Rosales, E. M ; Torres-Gómez, G</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a250t-684ef7b2d9acd4bbc1acb9f3a41bcde22a1225a393efe8a8e3de97381bb9bb1b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>Chemistry</topic><topic>Electrochemistry</topic><topic>Electrodes: preparations and properties</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Other electrodes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Casañ-Pastor, N</creatorcontrib><creatorcontrib>Zinck, C</creatorcontrib><creatorcontrib>Michel, C. R</creatorcontrib><creatorcontrib>Tejada-Rosales, E. M</creatorcontrib><creatorcontrib>Torres-Gómez, G</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><jtitle>Chemistry of materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Casañ-Pastor, N</au><au>Zinck, C</au><au>Michel, C. R</au><au>Tejada-Rosales, E. M</au><au>Torres-Gómez, G</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Evidence of Oxygen Intercalation and Mobility at Room Temperature in Oxides:  An Electrochemical Quartz Microbalance Study of Intercalation in La2CuO4</atitle><jtitle>Chemistry of materials</jtitle><addtitle>Chem. Mater</addtitle><date>2001-06-18</date><risdate>2001</risdate><volume>13</volume><issue>6</issue><spage>2118</spage><epage>2126</epage><pages>2118-2126</pages><issn>0897-4756</issn><eissn>1520-5002</eissn><abstract>This paper offers direct evidence for the electrochemical intercalation of oxygen in an oxide with the K2NiF4 structure, namely, La2CuO4, at room temperature. Organic solvents, as well as water, allow that reaction to occur. The charge-to-mass ratio evaluated from a comparison with fluoride intercalation implies that either OH- or Oδ- species are being intercalated. Comparison with previous work seems to favor the latter. If an oxygen with lower charge is moving, that could indeed explain why oxygen conductivity can be observed at such low temperatures.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/cm001404t</doi><tpages>9</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0897-4756
ispartof Chemistry of materials, 2001-06, Vol.13 (6), p.2118-2126
issn 0897-4756
1520-5002
language eng
recordid cdi_pascalfrancis_primary_1082554
source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Chemistry
Electrochemistry
Electrodes: preparations and properties
Exact sciences and technology
General and physical chemistry
Other electrodes
title Evidence of Oxygen Intercalation and Mobility at Room Temperature in Oxides:  An Electrochemical Quartz Microbalance Study of Intercalation in La2CuO4
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-13T21%3A33%3A28IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_pasca&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Evidence%20of%20Oxygen%20Intercalation%20and%20Mobility%20at%20Room%20Temperature%20in%20Oxides:%E2%80%89%20An%20Electrochemical%20Quartz%20Microbalance%20Study%20of%20Intercalation%20in%20La2CuO4&rft.jtitle=Chemistry%20of%20materials&rft.au=Casa%C3%B1-Pastor,%20N&rft.date=2001-06-18&rft.volume=13&rft.issue=6&rft.spage=2118&rft.epage=2126&rft.pages=2118-2126&rft.issn=0897-4756&rft.eissn=1520-5002&rft_id=info:doi/10.1021/cm001404t&rft_dat=%3Cacs_pasca%3Eb600275325%3C/acs_pasca%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a250t-684ef7b2d9acd4bbc1acb9f3a41bcde22a1225a393efe8a8e3de97381bb9bb1b3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true