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Crystal field analysis of different Er3+ sites in LiNbO3
The Er 3+ defect in lithium niobate (LiNbO 3 ), and the slightly different lattice environments ("sites") it experiences, have been investigated with combined excitation-emission spectroscopy under application of hydrostatic pressure and electric fields. The results give a solid basis for...
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Published in: | Radiation effects and defects in solids 2001-11, Vol.155 (1-4), p.253-258 |
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container_title | Radiation effects and defects in solids |
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creator | Dierolf, V. Sandmann, C. Kutsenko, A. B. Tröster, Th |
description | The Er
3+
defect in lithium niobate (LiNbO
3
), and the slightly different lattice environments ("sites") it experiences, have been investigated with combined excitation-emission spectroscopy under application of hydrostatic pressure and electric fields. The results give a solid basis for a crystal field analysis which yields site-specific crystal field parameters. We found that the Er
3+
sites can be classified into two groups. Firstly, the sites are distinct due to different relative arrangements of the nearest-neighbor oxygens and secondly they encounter to different local electric fields which are caused by charge compensators and other defects in a more distant neighborhood. |
doi_str_mv | 10.1080/10420150108214123 |
format | article |
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3+
defect in lithium niobate (LiNbO
3
), and the slightly different lattice environments ("sites") it experiences, have been investigated with combined excitation-emission spectroscopy under application of hydrostatic pressure and electric fields. The results give a solid basis for a crystal field analysis which yields site-specific crystal field parameters. We found that the Er
3+
sites can be classified into two groups. Firstly, the sites are distinct due to different relative arrangements of the nearest-neighbor oxygens and secondly they encounter to different local electric fields which are caused by charge compensators and other defects in a more distant neighborhood.</description><identifier>ISSN: 1042-0150</identifier><identifier>EISSN: 1029-4953</identifier><identifier>DOI: 10.1080/10420150108214123</identifier><identifier>CODEN: REDSEI</identifier><language>eng</language><publisher>Reading: Taylor & Francis Group</publisher><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Condensed matter: structure, mechanical and thermal properties ; Defects and impurities in crystals; microstructure ; Electron states ; Exact sciences and technology ; High pressure ; Indirect evidence of dislocations and other defects (resistivity, slip, creep, strains, internal friction, epr, nmr, etc.) ; Level splitting and interactions ; LiNbO ; Physics ; Site-selective spectroscopy ; Spin-orbit coupling, Zeeman and Stark splitting, Jahn-Teller effect ; Spin-orbit coupling, zeeman, stark, and strain splitting, jahn-teller effect ; Stark effect ; Structure of solids and liquids; crystallography</subject><ispartof>Radiation effects and defects in solids, 2001-11, Vol.155 (1-4), p.253-258</ispartof><rights>Copyright Taylor & Francis Group, LLC 2001</rights><rights>2002 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,780,784,789,790,23928,23929,25138,27922,27923</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=13420835$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Dierolf, V.</creatorcontrib><creatorcontrib>Sandmann, C.</creatorcontrib><creatorcontrib>Kutsenko, A. B.</creatorcontrib><creatorcontrib>Tröster, Th</creatorcontrib><title>Crystal field analysis of different Er3+ sites in LiNbO3</title><title>Radiation effects and defects in solids</title><description>The Er
3+
defect in lithium niobate (LiNbO
3
), and the slightly different lattice environments ("sites") it experiences, have been investigated with combined excitation-emission spectroscopy under application of hydrostatic pressure and electric fields. The results give a solid basis for a crystal field analysis which yields site-specific crystal field parameters. We found that the Er
3+
sites can be classified into two groups. Firstly, the sites are distinct due to different relative arrangements of the nearest-neighbor oxygens and secondly they encounter to different local electric fields which are caused by charge compensators and other defects in a more distant neighborhood.</description><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Defects and impurities in crystals; microstructure</subject><subject>Electron states</subject><subject>Exact sciences and technology</subject><subject>High pressure</subject><subject>Indirect evidence of dislocations and other defects (resistivity, slip, creep, strains, internal friction, epr, nmr, etc.)</subject><subject>Level splitting and interactions</subject><subject>LiNbO</subject><subject>Physics</subject><subject>Site-selective spectroscopy</subject><subject>Spin-orbit coupling, Zeeman and Stark splitting, Jahn-Teller effect</subject><subject>Spin-orbit coupling, zeeman, stark, and strain splitting, jahn-teller effect</subject><subject>Stark effect</subject><subject>Structure of solids and liquids; crystallography</subject><issn>1042-0150</issn><issn>1029-4953</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhoMoWKs_wFsunmR18rGbBLxIqR9Q7EXPy3STQCTdLUlA99-7pXrqwdPMwPO8MC8h1wzuGGi4ZyA5sBqmgzPJuDghMwbcVNLU4nS_S17tgXNykfMnAGip5YzoRRpzwUh9cNFS7DGOOWQ6eGqD9y65vtBlErc0h-IyDT1dhbfNWlySM48xu6vfOScfT8v3xUu1Wj-_Lh5XVeCsKRUqJbVRgFp3DqBDY5umZh0HW7PGK7fZ1JYbJRVqkJ3xqIAZprHxyLW3Yk5uDrk7zB1Gn7DvQm53KWwxjS0T099a1BOnDlzo_ZC2-DWkaNuCYxzSn3RUUlu-y2Q-_GsKBu2-5-MI8QMQmWz1</recordid><startdate>20011101</startdate><enddate>20011101</enddate><creator>Dierolf, V.</creator><creator>Sandmann, C.</creator><creator>Kutsenko, A. B.</creator><creator>Tröster, Th</creator><general>Taylor & Francis Group</general><general>Taylor and Francis</general><scope>IQODW</scope></search><sort><creationdate>20011101</creationdate><title>Crystal field analysis of different Er3+ sites in LiNbO3</title><author>Dierolf, V. ; Sandmann, C. ; Kutsenko, A. B. ; Tröster, Th</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i216t-a7748970a88ce00ca9d6651c20d516f7ebb5d29747a804c9fa701918a6fa28fd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Defects and impurities in crystals; microstructure</topic><topic>Electron states</topic><topic>Exact sciences and technology</topic><topic>High pressure</topic><topic>Indirect evidence of dislocations and other defects (resistivity, slip, creep, strains, internal friction, epr, nmr, etc.)</topic><topic>Level splitting and interactions</topic><topic>LiNbO</topic><topic>Physics</topic><topic>Site-selective spectroscopy</topic><topic>Spin-orbit coupling, Zeeman and Stark splitting, Jahn-Teller effect</topic><topic>Spin-orbit coupling, zeeman, stark, and strain splitting, jahn-teller effect</topic><topic>Stark effect</topic><topic>Structure of solids and liquids; crystallography</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dierolf, V.</creatorcontrib><creatorcontrib>Sandmann, C.</creatorcontrib><creatorcontrib>Kutsenko, A. B.</creatorcontrib><creatorcontrib>Tröster, Th</creatorcontrib><collection>Pascal-Francis</collection><jtitle>Radiation effects and defects in solids</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dierolf, V.</au><au>Sandmann, C.</au><au>Kutsenko, A. B.</au><au>Tröster, Th</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal field analysis of different Er3+ sites in LiNbO3</atitle><jtitle>Radiation effects and defects in solids</jtitle><date>2001-11-01</date><risdate>2001</risdate><volume>155</volume><issue>1-4</issue><spage>253</spage><epage>258</epage><pages>253-258</pages><issn>1042-0150</issn><eissn>1029-4953</eissn><coden>REDSEI</coden><abstract>The Er
3+
defect in lithium niobate (LiNbO
3
), and the slightly different lattice environments ("sites") it experiences, have been investigated with combined excitation-emission spectroscopy under application of hydrostatic pressure and electric fields. The results give a solid basis for a crystal field analysis which yields site-specific crystal field parameters. We found that the Er
3+
sites can be classified into two groups. Firstly, the sites are distinct due to different relative arrangements of the nearest-neighbor oxygens and secondly they encounter to different local electric fields which are caused by charge compensators and other defects in a more distant neighborhood.</abstract><cop>Reading</cop><pub>Taylor & Francis Group</pub><doi>10.1080/10420150108214123</doi><tpages>6</tpages></addata></record> |
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subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Defects and impurities in crystals microstructure Electron states Exact sciences and technology High pressure Indirect evidence of dislocations and other defects (resistivity, slip, creep, strains, internal friction, epr, nmr, etc.) Level splitting and interactions LiNbO Physics Site-selective spectroscopy Spin-orbit coupling, Zeeman and Stark splitting, Jahn-Teller effect Spin-orbit coupling, zeeman, stark, and strain splitting, jahn-teller effect Stark effect Structure of solids and liquids crystallography |
title | Crystal field analysis of different Er3+ sites in LiNbO3 |
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