Correlation, verification and prediction of vapour–liquid equilibria using equation of state with association term: II. Alcohols + non-aliphatic hydrocarbons

An equation of state with association term was used to correlate all available binary VLE data sets for mixtures of alkanols with non-aliphatic hydrocarbons. The self association of alkanols was described using a uniform set of parameters. The cross association between alkanols and aromatic compound...

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Bibliographic Details
Published in:Fluid phase equilibria 2002-01, Vol.193 (1), p.97-107
Main Author: GORAL, M
Format: Article
Language:English
Subjects:
Alkanols
Association
Chemistry
Equation of state
Exact sciences and technology
General and physical chemistry
Hydrocarbons
Liquid-vapor equilibria
Phase equilibria
Vapour–liquid equilibria
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Summary:An equation of state with association term was used to correlate all available binary VLE data sets for mixtures of alkanols with non-aliphatic hydrocarbons. The self association of alkanols was described using a uniform set of parameters. The cross association between alkanols and aromatic compounds was taken into account. The verification of the VLE data for mixtures of alkanols and non-aliphatic hydrocarbons is described and recommended data are given. The method of prediction of the VLE in the investigated mixtures is described. The recommended data were compared with the results of the prediction.
ISSN:0378-3812
1879-0224
DOI:10.1016/S0378-3812(01)00641-0