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Interfacial reactions between lead-free SnAgCu solder and Ni(P) surface finish on printed circuit boards
Transmission electron microscopy and scanning electron microscopy were employed to analyze the interfacial microstructure between Sn-Ag-Cu solder alloys and Ni(P)/Au metallizations. The intermetallic compound Cu/sub 6/Sn/sub 5/, containing a small amount of dissolved Ni, was found to form preferenti...
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Published in: | IEEE transactions on electronics packaging manufacturing 2002-07, Vol.25 (3), p.162-167 |
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creator | Kejun Zeng Vuorinen, V. Kivilahti, J.K. |
description | Transmission electron microscopy and scanning electron microscopy were employed to analyze the interfacial microstructure between Sn-Ag-Cu solder alloys and Ni(P)/Au metallizations. The intermetallic compound Cu/sub 6/Sn/sub 5/, containing a small amount of dissolved Ni, was found to form preferentially on the Ni coating. This compound layer served as a barrier for direct reaction of Sn with the Ni(P) coating. On the Ni(P) side, a nickel phosphide was identified. Thermodynamic evaluation of the Cu-Ni-Sn system was carried out to rationalize the enrichment of Cu at the solder/finish interface. Effects of the interfacial reactions on joint reliability are discussed. |
doi_str_mv | 10.1109/TEPM.2002.801648 |
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The intermetallic compound Cu/sub 6/Sn/sub 5/, containing a small amount of dissolved Ni, was found to form preferentially on the Ni coating. This compound layer served as a barrier for direct reaction of Sn with the Ni(P) coating. On the Ni(P) side, a nickel phosphide was identified. Thermodynamic evaluation of the Cu-Ni-Sn system was carried out to rationalize the enrichment of Cu at the solder/finish interface. Effects of the interfacial reactions on joint reliability are discussed.</description><identifier>ISSN: 1521-334X</identifier><identifier>EISSN: 1558-0822</identifier><identifier>DOI: 10.1109/TEPM.2002.801648</identifier><identifier>CODEN: ITEPFL</identifier><language>eng</language><publisher>New York, NY: IEEE</publisher><subject>Applied sciences ; Boards ; Coating ; Coatings ; Copper ; Design. Technologies. Operation analysis. Testing ; Electronic equipment and fabrication. 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The intermetallic compound Cu/sub 6/Sn/sub 5/, containing a small amount of dissolved Ni, was found to form preferentially on the Ni coating. This compound layer served as a barrier for direct reaction of Sn with the Ni(P) coating. On the Ni(P) side, a nickel phosphide was identified. Thermodynamic evaluation of the Cu-Ni-Sn system was carried out to rationalize the enrichment of Cu at the solder/finish interface. Effects of the interfacial reactions on joint reliability are discussed.</description><subject>Applied sciences</subject><subject>Boards</subject><subject>Coating</subject><subject>Coatings</subject><subject>Copper</subject><subject>Design. Technologies. Operation analysis. Testing</subject><subject>Electronic equipment and fabrication. Passive components, printed wiring boards, connectics</subject><subject>Electronics</subject><subject>Environmentally friendly manufacturing techniques</subject><subject>Exact sciences and technology</subject><subject>Finishes</subject><subject>Integrated circuits</subject><subject>Interface reactions</subject><subject>Intermetallic compounds</subject><subject>Lead</subject><subject>Microelectronic fabrication (materials and surfaces technology)</subject><subject>Microstructure</subject><subject>Nickel</subject><subject>Printed circuits</subject><subject>Scanning electron microscopy</subject><subject>Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices</subject><subject>Solders</subject><subject>Surface finishing</subject><subject>Testing, measurement, noise and reliability</subject><subject>Tin</subject><subject>Transmission electron microscopy</subject><issn>1521-334X</issn><issn>1558-0822</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNqNkc9r10AQxYNYsFbvgpdF0OohX2d_JbvH8qXVQtWCFbwts5uJ3ZJu6m5C6X9vwrdQ8KA9zcB83mN4r6pecdhwDvbjxfH5l40AEBsDvFHmSbXPtTY1GCGerrvgtZTq57PqeSlXAFxpIfary9M0Ue4xRBxYJgxTHFNhnqZbosQGwq7uMxH7no5-bWdWxqGjzDB17Gt8f_6BlXlVE-tjiuWSjYnd5Lh4dizEHOY4MT9i7sqLaq_HodDL-3lQ_Tg5vth-rs--fTrdHp3VQYOdaq46wUmLtu15p8lY7lurdR-UQd-Y1sM6VEDlSaJG2YH2An2Q5KmxrTyoDne-N3n8PVOZ3HUsgYYBE41zcRZaa8FKvpDv_kkKqxoplPg_aAxIY-wjQGUaCeuTb_4Cr8Y5pyUXZ4xSUqt2dYMdFPJYSqbeLcleY75zHNzauVs7d2vnbtf5Inl774sl4NBnTCGWB51SojG8WbjXOy4S0cOZa2NEI_8AqzGz_w</recordid><startdate>20020701</startdate><enddate>20020701</enddate><creator>Kejun Zeng</creator><creator>Vuorinen, V.</creator><creator>Kivilahti, J.K.</creator><general>IEEE</general><general>Institute of Electrical and Electronics Engineers</general><general>The Institute of Electrical and Electronics Engineers, Inc. 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Passive components, printed wiring boards, connectics</topic><topic>Electronics</topic><topic>Environmentally friendly manufacturing techniques</topic><topic>Exact sciences and technology</topic><topic>Finishes</topic><topic>Integrated circuits</topic><topic>Interface reactions</topic><topic>Intermetallic compounds</topic><topic>Lead</topic><topic>Microelectronic fabrication (materials and surfaces technology)</topic><topic>Microstructure</topic><topic>Nickel</topic><topic>Printed circuits</topic><topic>Scanning electron microscopy</topic><topic>Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices</topic><topic>Solders</topic><topic>Surface finishing</topic><topic>Testing, measurement, noise and reliability</topic><topic>Tin</topic><topic>Transmission electron microscopy</topic><toplevel>online_resources</toplevel><creatorcontrib>Kejun Zeng</creatorcontrib><creatorcontrib>Vuorinen, V.</creatorcontrib><creatorcontrib>Kivilahti, J.K.</creatorcontrib><collection>IEEE All-Society Periodicals Package (ASPP) 1998-Present</collection><collection>IEEE Xplore</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>METADEX</collection><collection>Materials Research Database</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Engineering Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><jtitle>IEEE transactions on electronics packaging manufacturing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kejun Zeng</au><au>Vuorinen, V.</au><au>Kivilahti, J.K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Interfacial reactions between lead-free SnAgCu solder and Ni(P) surface finish on printed circuit boards</atitle><jtitle>IEEE transactions on electronics packaging manufacturing</jtitle><stitle>TEPM</stitle><date>2002-07-01</date><risdate>2002</risdate><volume>25</volume><issue>3</issue><spage>162</spage><epage>167</epage><pages>162-167</pages><issn>1521-334X</issn><eissn>1558-0822</eissn><coden>ITEPFL</coden><abstract>Transmission electron microscopy and scanning electron microscopy were employed to analyze the interfacial microstructure between Sn-Ag-Cu solder alloys and Ni(P)/Au metallizations. The intermetallic compound Cu/sub 6/Sn/sub 5/, containing a small amount of dissolved Ni, was found to form preferentially on the Ni coating. This compound layer served as a barrier for direct reaction of Sn with the Ni(P) coating. On the Ni(P) side, a nickel phosphide was identified. Thermodynamic evaluation of the Cu-Ni-Sn system was carried out to rationalize the enrichment of Cu at the solder/finish interface. Effects of the interfacial reactions on joint reliability are discussed.</abstract><cop>New York, NY</cop><pub>IEEE</pub><doi>10.1109/TEPM.2002.801648</doi><tpages>6</tpages></addata></record> |
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subjects | Applied sciences Boards Coating Coatings Copper Design. Technologies. Operation analysis. Testing Electronic equipment and fabrication. Passive components, printed wiring boards, connectics Electronics Environmentally friendly manufacturing techniques Exact sciences and technology Finishes Integrated circuits Interface reactions Intermetallic compounds Lead Microelectronic fabrication (materials and surfaces technology) Microstructure Nickel Printed circuits Scanning electron microscopy Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices Solders Surface finishing Testing, measurement, noise and reliability Tin Transmission electron microscopy |
title | Interfacial reactions between lead-free SnAgCu solder and Ni(P) surface finish on printed circuit boards |
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