A 207Pb NMR study of the adducts of triphenyllead chloride and diphenyllead dichloride

207Pb NMR spectra were used to determine the structure of adducts of triphenyllead chloride and diphenyllead dichloride in CH2Cl2 and CH3CN. The bases included several phosphorus donors, such as tributylphosphine, oxygen donors, such as tributylphosphine oxide, and nitrogen donors, such as pyridine....

Full description

Saved in:
Bibliographic Details
Published in:Applied organometallic chemistry 2003-04, Vol.17 (4), p.236-238
Main Authors: Margolis, Lara A., Schaeffer Jr, Charles D., Yoder, Claude H.
Format: Article
Language:English
Subjects:
207Pb
adduct
Chemistry
Exact sciences and technology
Ge, sn, pb derivatives
lead
Lewis acid
NMR
Organic chemistry
Organometalloidal and organometallic compounds
Preparations and properties
triphenyllead chloride
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 238
container_issue 4
container_start_page 236
container_title Applied organometallic chemistry
container_volume 17
creator Margolis, Lara A.
Schaeffer Jr, Charles D.
Yoder, Claude H.
description 207Pb NMR spectra were used to determine the structure of adducts of triphenyllead chloride and diphenyllead dichloride in CH2Cl2 and CH3CN. The bases included several phosphorus donors, such as tributylphosphine, oxygen donors, such as tributylphosphine oxide, and nitrogen donors, such as pyridine. A number of bidentate bases were also studied. The 207Pb spectra indicate that rapid exchange occurs in the adducts, even at temperatures of −90 °C. The magnitude of the shift relative to the lead acid indicates that all of the bases, including the bidentate bases, form five‐coordinate adducts with triphenyllead chloride. Diphenyllead dichloride forms six‐coordinate adducts, except for the adduct with tributylphosphine, which is five‐coordinate. This is the first report of a five‐coordinate adduct of diphenyllead dichloride. Copyright © 2003 John Wiley & Sons, Ltd.
doi_str_mv 10.1002/aoc.412
format article
fullrecord <record><control><sourceid>istex_pasca</sourceid><recordid>TN_cdi_pascalfrancis_primary_14620843</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_WNG_F3958Z47_G</sourcerecordid><originalsourceid>FETCH-LOGICAL-i1042-560f976201c0806e5c55068df1d813cd3eb98519f7be6a101eb80ccd78764f2e3</originalsourceid><addsrcrecordid>eNpNkEtLAzEYRYMoWKv4F7JxJVO_JJPXshRbhdqK-AA3IZNkaHRsy2SKnX_vaH2tLpd7uIuD0CmBAQGgF3blBjmhe6hHQOsMJNP7qAdUqIwK4IfoKKUXANCC5D30OMQU5G2BZzd3ODUb3-JViZtFwNb7jWvSV63jehGWbVUF67FbVKs6-o5Yeuz_Lz7-bMfooLRVCiff2UcP48v70VU2nU-uR8NpFgnkNOMCSi0FBeJAgQjccQ5C-ZJ4RZjzLBRacaJLWQRhCZBQKHDOSyVFXtLA-uhs97u2ydmqrO3SxWTWdXyzdWtI3n2rnHXc-Y57j1Vo_3Ywn85M58x0zsxwPuqio7MdHVMTtr-0rV-NkExy8zSbmDHTXD3n0kzYB6fObbs</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A 207Pb NMR study of the adducts of triphenyllead chloride and diphenyllead dichloride</title><source>Wiley</source><creator>Margolis, Lara A. ; Schaeffer Jr, Charles D. ; Yoder, Claude H.</creator><creatorcontrib>Margolis, Lara A. ; Schaeffer Jr, Charles D. ; Yoder, Claude H.</creatorcontrib><description>207Pb NMR spectra were used to determine the structure of adducts of triphenyllead chloride and diphenyllead dichloride in CH2Cl2 and CH3CN. The bases included several phosphorus donors, such as tributylphosphine, oxygen donors, such as tributylphosphine oxide, and nitrogen donors, such as pyridine. A number of bidentate bases were also studied. The 207Pb spectra indicate that rapid exchange occurs in the adducts, even at temperatures of −90 °C. The magnitude of the shift relative to the lead acid indicates that all of the bases, including the bidentate bases, form five‐coordinate adducts with triphenyllead chloride. Diphenyllead dichloride forms six‐coordinate adducts, except for the adduct with tributylphosphine, which is five‐coordinate. This is the first report of a five‐coordinate adduct of diphenyllead dichloride. Copyright © 2003 John Wiley &amp; Sons, Ltd.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.412</identifier><identifier>CODEN: AOCHEX</identifier><language>eng</language><publisher>Chichester, UK: John Wiley &amp; Sons, Ltd</publisher><subject>207Pb ; adduct ; Chemistry ; Exact sciences and technology ; Ge, sn, pb derivatives ; lead ; Lewis acid ; NMR ; Organic chemistry ; Organometalloidal and organometallic compounds ; Preparations and properties ; triphenyllead chloride</subject><ispartof>Applied organometallic chemistry, 2003-04, Vol.17 (4), p.236-238</ispartof><rights>Copyright © 2003 John Wiley &amp; Sons, Ltd.</rights><rights>2003 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=14620843$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Margolis, Lara A.</creatorcontrib><creatorcontrib>Schaeffer Jr, Charles D.</creatorcontrib><creatorcontrib>Yoder, Claude H.</creatorcontrib><title>A 207Pb NMR study of the adducts of triphenyllead chloride and diphenyllead dichloride</title><title>Applied organometallic chemistry</title><addtitle>Appl. Organometal. Chem</addtitle><description>207Pb NMR spectra were used to determine the structure of adducts of triphenyllead chloride and diphenyllead dichloride in CH2Cl2 and CH3CN. The bases included several phosphorus donors, such as tributylphosphine, oxygen donors, such as tributylphosphine oxide, and nitrogen donors, such as pyridine. A number of bidentate bases were also studied. The 207Pb spectra indicate that rapid exchange occurs in the adducts, even at temperatures of −90 °C. The magnitude of the shift relative to the lead acid indicates that all of the bases, including the bidentate bases, form five‐coordinate adducts with triphenyllead chloride. Diphenyllead dichloride forms six‐coordinate adducts, except for the adduct with tributylphosphine, which is five‐coordinate. This is the first report of a five‐coordinate adduct of diphenyllead dichloride. Copyright © 2003 John Wiley &amp; Sons, Ltd.</description><subject>207Pb</subject><subject>adduct</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Ge, sn, pb derivatives</subject><subject>lead</subject><subject>Lewis acid</subject><subject>NMR</subject><subject>Organic chemistry</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Preparations and properties</subject><subject>triphenyllead chloride</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNpNkEtLAzEYRYMoWKv4F7JxJVO_JJPXshRbhdqK-AA3IZNkaHRsy2SKnX_vaH2tLpd7uIuD0CmBAQGgF3blBjmhe6hHQOsMJNP7qAdUqIwK4IfoKKUXANCC5D30OMQU5G2BZzd3ODUb3-JViZtFwNb7jWvSV63jehGWbVUF67FbVKs6-o5Yeuz_Lz7-bMfooLRVCiff2UcP48v70VU2nU-uR8NpFgnkNOMCSi0FBeJAgQjccQ5C-ZJ4RZjzLBRacaJLWQRhCZBQKHDOSyVFXtLA-uhs97u2ydmqrO3SxWTWdXyzdWtI3n2rnHXc-Y57j1Vo_3Ywn85M58x0zsxwPuqio7MdHVMTtr-0rV-NkExy8zSbmDHTXD3n0kzYB6fObbs</recordid><startdate>200304</startdate><enddate>200304</enddate><creator>Margolis, Lara A.</creator><creator>Schaeffer Jr, Charles D.</creator><creator>Yoder, Claude H.</creator><general>John Wiley &amp; Sons, Ltd</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope></search><sort><creationdate>200304</creationdate><title>A 207Pb NMR study of the adducts of triphenyllead chloride and diphenyllead dichloride</title><author>Margolis, Lara A. ; Schaeffer Jr, Charles D. ; Yoder, Claude H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i1042-560f976201c0806e5c55068df1d813cd3eb98519f7be6a101eb80ccd78764f2e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>207Pb</topic><topic>adduct</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Ge, sn, pb derivatives</topic><topic>lead</topic><topic>Lewis acid</topic><topic>NMR</topic><topic>Organic chemistry</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Preparations and properties</topic><topic>triphenyllead chloride</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Margolis, Lara A.</creatorcontrib><creatorcontrib>Schaeffer Jr, Charles D.</creatorcontrib><creatorcontrib>Yoder, Claude H.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Margolis, Lara A.</au><au>Schaeffer Jr, Charles D.</au><au>Yoder, Claude H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A 207Pb NMR study of the adducts of triphenyllead chloride and diphenyllead dichloride</atitle><jtitle>Applied organometallic chemistry</jtitle><addtitle>Appl. Organometal. Chem</addtitle><date>2003-04</date><risdate>2003</risdate><volume>17</volume><issue>4</issue><spage>236</spage><epage>238</epage><pages>236-238</pages><issn>0268-2605</issn><eissn>1099-0739</eissn><coden>AOCHEX</coden><abstract>207Pb NMR spectra were used to determine the structure of adducts of triphenyllead chloride and diphenyllead dichloride in CH2Cl2 and CH3CN. The bases included several phosphorus donors, such as tributylphosphine, oxygen donors, such as tributylphosphine oxide, and nitrogen donors, such as pyridine. A number of bidentate bases were also studied. The 207Pb spectra indicate that rapid exchange occurs in the adducts, even at temperatures of −90 °C. The magnitude of the shift relative to the lead acid indicates that all of the bases, including the bidentate bases, form five‐coordinate adducts with triphenyllead chloride. Diphenyllead dichloride forms six‐coordinate adducts, except for the adduct with tributylphosphine, which is five‐coordinate. This is the first report of a five‐coordinate adduct of diphenyllead dichloride. Copyright © 2003 John Wiley &amp; Sons, Ltd.</abstract><cop>Chichester, UK</cop><pub>John Wiley &amp; Sons, Ltd</pub><doi>10.1002/aoc.412</doi><tpages>3</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0268-2605
ispartof Applied organometallic chemistry, 2003-04, Vol.17 (4), p.236-238
issn 0268-2605
1099-0739
language eng
recordid cdi_pascalfrancis_primary_14620843
source Wiley
subjects 207Pb
adduct
Chemistry
Exact sciences and technology
Ge, sn, pb derivatives
lead
Lewis acid
NMR
Organic chemistry
Organometalloidal and organometallic compounds
Preparations and properties
triphenyllead chloride
title A 207Pb NMR study of the adducts of triphenyllead chloride and diphenyllead dichloride
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T03%3A25%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_pasca&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20207Pb%20NMR%20study%20of%20the%20adducts%20of%20triphenyllead%20chloride%20and%20diphenyllead%20dichloride&rft.jtitle=Applied%20organometallic%20chemistry&rft.au=Margolis,%20Lara%20A.&rft.date=2003-04&rft.volume=17&rft.issue=4&rft.spage=236&rft.epage=238&rft.pages=236-238&rft.issn=0268-2605&rft.eissn=1099-0739&rft.coden=AOCHEX&rft_id=info:doi/10.1002/aoc.412&rft_dat=%3Cistex_pasca%3Eark_67375_WNG_F3958Z47_G%3C/istex_pasca%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-i1042-560f976201c0806e5c55068df1d813cd3eb98519f7be6a101eb80ccd78764f2e3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true