Excess molar enthalpies of binary mixtures of 1-hexene with some cyclic and aromatic hydrocarbons at 298.15 K

Microcalorimetric measurements of excess molar enthalpies, at 298.15 K, are reported for the four binary systems formed by mixing 1-hexene with the cycloalkanes: cyclohexane and methylcyclohexane, and with the aromatic hydrocarcons: benzene and toluene. Smooth Redlich–Kister representations of the r...

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Bibliographic Details
Published in:Thermochimica acta 2004-05, Vol.414 (1), p.31-33
Main Authors: Wang, Zhaohui, Benson, George C., Lu, Benjamin C.-Y.
Format: Article
Language:English
Subjects:
1-Hexene
Benzene
Binnary system
Chemical thermodynamics
Chemistry
Cyclohexane
Exact sciences and technology
Excess molar enthalpy
General and physical chemistry
General. Theory
Liebermann–Fried model
Methylcyclohexane
Toluene
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Summary:Microcalorimetric measurements of excess molar enthalpies, at 298.15 K, are reported for the four binary systems formed by mixing 1-hexene with the cycloalkanes: cyclohexane and methylcyclohexane, and with the aromatic hydrocarcons: benzene and toluene. Smooth Redlich–Kister representations of the results are presented. It was found that the Liebermann–Fried model also provided good representations of the results.
ISSN:0040-6031
1872-762X
DOI:10.1016/j.tca.2003.10.010