Catalytic combustion of particulate matter: Catalysts of alkaline nitrates supported on hydrous zirconium

• Published in: Thermochimica acta 2004-11, Vol.421 (1), p.117-121
• Main Authors: Galdeano, N.F., Carrascull, A.L., Ponzi, M.I., Lick, I.D., Ponzi, E.N.
• Format: Article
• Language: English
• Subjects: Alkaline metals; Chemistry; Combustion. Flame; DSC; Exact sciences and technology; General and physical chemistry; Hydrous zirconium; Soot; TGA
• ISSN: 0040-6031; 1872-762X
• DOI: 10.1016/j.tca.2004.04.006

In order to explore a method to remove particulate matter, catalysts of different alkaline nitrates (Li, K and Cs) supported on hydrous zirconium were prepared by the method of incipient humidity and tested as catalysts for particulate matter combustion. The catalytic activity was determined by using the temperature programmed oxidation technique (TPO), utilizing two equipments, a thermogravimetric reactor and other of fixed bed. In the first case the particulate matter/catalyst mixture was milled carefully in a mortar (tight contact) while in the second case more realistic operative conditions were used, particulate matter/catalyst mixture was made with a spatula (loose contact). All prepared catalysts showed good activity for the particulate matter combustion. The cesium catalyst was the one that presented higher activity, decreasing the combustion temperature between 200 and 250 °C with respect to the combustion without catalyst. The catalyst with lithium nitrate became active at higher temperature than its melting point and the same occurred with the potassium catalyst. This did not occur for the catalyst containing cesium nitrate that melts at 407 °C and became active from 350 °C.