A study of the effects of SSL on the adhesion property of phenolic resin in production of agro-based composite

• Published in: Pigment & resin technology 2006-01, Vol.35 (3), p.137-146
• Main Authors: El-Saied, H, Basta, A.H
• Format: Article
• Language: English
• Subjects: Adhesives; Applied sciences; Cellulose; Composite materials; Exact sciences and technology; Fibers and threads; Forms of application and semi-finished materials; Hot pressing; Lignin; Lignocellulose; Liquor; Phenols; Polymer industry, paints, wood; Resins; Sodium; Technology of polymers; Wood products
• ISSN: 0369-9420; 1758-6941
• DOI: 10.1108/03699420610665166

Purpose - To investigate the role of spent sulphite liquor (SSL) retained on neutral sulphite bagasse pulp in the binding action of phenolic resin, for the purpose of enhancing its performance to produce high quality agro-based composite.Design methodology approach - Pulps used in this work as agro-based fibres were prepared from Asplund defibrator and neutral sulphite pulping processes. The performance of the resol resin in presence of SSL, were evaluated in terms of the effects of SSL constituents and using novolac as phenolic resin, in comparison with that prepared from pulps in absence of SSL and conventionally prepared resol - Asplund bagasse composites. Preparation of pulp free from sulphonyl groups and pre-out-precipitating the resol or lignosulphonic acid (LSA) on the strength and water resistance properties of the composite produced was also examined. The degraded hemicellulose and LSA in SSL were polynomial correlated with the changes in composites properties.Findings - All neutral sulphite pulps investigated, in presence of SSL, were found to enhance the strength quality of agro-based composite compared to commercially available resol-agro-based composite. The retained SSL on NS-raw bagasse pulp could replace the Asplund bagasse pulp together with resol resin in production of agro-composite. As well as, using neutral sulphite - Asplund bagasse pulp reduced the percent of added resol to half, to produce commercial resol agro-based composite. The performance of the composite produced from novolac resin-SSL-neutral sulphite pulp and resol-LSA-neutral sulphite pulp exceeded 1.5 to 1.9 times the strength of commercially available composite.Research limitations implications - Despite the SSL retained on pulp success in improving the strength property of the resol resin-agro-composites, but it has an undesirable effect on water resistance of the product. This problem was resolved by avoiding the undesirable effect of sulphonyl groups on pulp fibres as well as the degraded hemicellulose in SSL.Practical implications - The approach developed provided a simple and practical solution to enhancing the performance of phenolic resin as well as agro-fibres and SSL wastes in the production of high performance lignocellulosic composite.Originality value - The resol, together with SSL constituents retained on neutral sulphite pulp, are economic bonding agents for agro-fibres and could be used in wood mills for production of medium density fibre-board.