Characterization of Starch/Acrylic Acid Super-Absorbent Hydrogels Prepared by Ionizing Radiation

• Published in: Journal of macromolecular science. Part A, Pure and applied chemistry Pure and applied chemistry, 2006-06, Vol.43 (7), p.1051-1063
• Main Authors: El-Mohdy, H. L. Abd, Hegazy, El-Sayed A., Abd El-Rehim, H. A.
• Format: Article
• Language: English
• Subjects: Applied sciences; copolymerization; Exact sciences and technology; Grafting and modifications; hydrogel; Physicochemistry of polymers; Polymers and radiations; radiation; starch; superabsorbent
• ISSN: 1060-1325; 1520-5738
• DOI: 10.1080/10601320600740249

Copolymerization of acrylic acid (AAc) and gelatinized maize starch in aqueous medium using γ-irradiation, followed by neutralization with alkali solution was carried out. The preparation conditions, such as irradiation dose and starch/AAc compositions were investigated. The higher the irradiation dose, as well as the AAc content in the feed solution, the higher the gel content. The copolymers were characterized by FTIR spectroscopy, thermo-gravimetric analysis (TGA) and scanning electron microscopy (SEM). SEM revealed that the higher the dose, the lower the copolymer pore size. Starch/AAc copolymers have thermal stability higher than that for starch and poly acrylic acid individually. The swelling of starch/AAc hydrogels reduced as the gel content increases. The maximum water absorption obtained for starch/AAc hydrogels in distilled water was 200 g/g, and for neutralized starch/AAc hydrogels was 350 g/g. The swelling ratio of starch/AAc hydrogels of different compositions in NaCl solution is lower than that obtained in distilled water. The results suggest that the neutralized starch/AAc hydrogels have a high swelling property, and can be used in a variety of commercial applications.