Hydrothermal Synthesis of Bi2WO6 Uniform Hierarchical Microspheres

• Published in: Crystal growth & design 2007-07, Vol.7 (7), p.1350-1355
• Main Authors: Li, Yuanyuan, Liu, Jinping, Huang, Xintang, Li, Guangyun
• Format: Article
• Language: English
• Subjects: Chemical synthesis methods; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Exact sciences and technology; Inorganic compounds; Materials science; Methods of nanofabrication; Nanoscale materials and structures: fabrication and characterization; Other topics in nanoscale materials and structures; Physics; Single-crystal and powder diffraction; Structure of solids and liquids; crystallography; Structure of specific crystalline solids; X-ray diffraction and scattering
• ISSN: 1528-7483; 1528-7505
• DOI: 10.1021/cg070343+

Bi2WO6 uniform hierarchical microspheres were grown on a large scale at 180 °C by a simple hydrothermal method with the help of the surfactant poly(vinyl pyrrolidone) (PVP). X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and high-resolution transmission electron microscopy (HRTEM) were used to characterize the product. The result indicated that three-dimensional (3D) Bi2WO6 microspheres were constructed layer-by-layer from a large number of two-dimensional (2D) sheets, which were composed of numerous interconnected square nanoplates with a mean side length of 65 nm. Pore-size distribution analysis showed that both mesopores and macropores existed in the 3D microstructures. The formation mechanism was discussed on the basis of the results of time-dependent experiments. It was demonstrated that PVP played a key role in the formation of such hierarchical microspheres. By adjusting the amount of PVP, Bi2WO6 with different morphologies can be attained accordingly. UV−vis spectroscopy was further employed to estimate the band gap energy of the hierarchical structures. Our work may shed some light on the design of other well-defined complex nanostructures, and the as-grown architectures may have potential applications.