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Using of Modified Plastic Waste Based on Poly(ethylene-co-acrylic acid) Grafts to Solve Transportation Problem of Petroleum Crude Oil

Polyethylene acrylic acid copolymer (PEAA) was modified with different types of alkanols and hydroxybenzoic acids to produce three types of esterified grafts. The molecular structures of the synthesized dispersants were performed using 1 H NMR analysis. The molecular weights of the synthesized dispe...

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Published in:Journal of dispersion science and technology 2008-01, Vol.29 (1), p.7-19
Main Authors: Atta, Ayman M., Elsockary, Maher A., Kandil, Osama F., Mohamed, Zakaa M.
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Language:English
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cited_by cdi_FETCH-LOGICAL-c444t-21f7bb762aead32117c39bbfb846d69dfa66a380bac6e03a5c95213b209291fe3
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description Polyethylene acrylic acid copolymer (PEAA) was modified with different types of alkanols and hydroxybenzoic acids to produce three types of esterified grafts. The molecular structures of the synthesized dispersants were performed using 1 H NMR analysis. The molecular weights of the synthesized dispersants were determined by GPC technique. The activity of PEAA derivatives as asphaltene stabilizer in the crude oil was evaluated by means of flocculation measurements. The effect of asphaltenes on the rheological behavior of highly asphaltenic crude oils was studied to evaluate the transportation parameters of crude oils. The rheological properties were measured at different temperature ranges of 5°C to 25°C in presence and absence of PEAA additives. It was observed that the PEAA having side chain lengths below C 16 show non-Newtonian pseudoplastic relationships at temperatures from 25°C to 5°C. While, PEAA additives having side chain lengths equal or above C 16 show Newtonian relationship even at low temperature (5°C) for all tested crude oils.
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identifier ISSN: 0193-2691
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source Taylor and Francis Science and Technology Collection
subjects Applied sciences
Asphaltene dispersant
Chemistry
Colloidal state and disperse state
crude oil
Exact sciences and technology
flow improver
General and physical chemistry
Physicochemistry of polymers
plastic waste
polyethylene acrylic acid
Polymer industry, paints, wood
rheology
transportation
title Using of Modified Plastic Waste Based on Poly(ethylene-co-acrylic acid) Grafts to Solve Transportation Problem of Petroleum Crude Oil
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