Kinetics and mechanism of reaction between acrylic acid or methacrylic acid and some oxiranes in the presence of N, N-dimethylaniline catalyst

The reactions of acrylic and methacrylic acids in ethylene oxide, propylene oxide, or glycerin epichlorohydrin were carried out in DMF in the presence of N, N‐dimethylaniline catalyst. The kinetic equations describing these equations have been devised and activation parameters ΔH#, ΔS#, and ΔG# calc...

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Bibliographic Details
Published in:Journal of chemical technology and biotechnology (1986) 1998-06, Vol.72 (2), p.117-124
Main Authors: Kucharski, Mieczysław, Lubczak, Renata
Format: Article
Language:English
Subjects:
acrylic acids
Catalysis
Catalytic reactions
Chemistry
Exact sciences and technology
General and physical chemistry
kinetic models
oxiranes
reaction mechanism
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Summary:The reactions of acrylic and methacrylic acids in ethylene oxide, propylene oxide, or glycerin epichlorohydrin were carried out in DMF in the presence of N, N‐dimethylaniline catalyst. The kinetic equations describing these equations have been devised and activation parameters ΔH#, ΔS#, and ΔG# calculated. The mechanism of the reaction has been proposed and verified by using kinetic and instrumental methods © 1998 SCI
ISSN:0268-2575
1097-4660
DOI:10.1002/(SICI)1097-4660(199806)72:2<117::AID-JCTB892>3.0.CO;2-Y