Heat Capacity and Standard Thermodynamic Functions of the Wulfenite PbMoO4 over the Temperature Range of (0 to 320) K

The heat capacity of natural lead molybdate (wulfenite, PbMoO4) has been measured by the method of vacuum adiabatic calorimetry over the temperature range of (4.3 to 80) K, and its thermodynamic functions in the range from (0 to 320) K have been calculated. The obtained standard values are as follow...

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Published in:Journal of chemical and engineering data 2011-05, Vol.56 (5), p.1941-1945
Main Authors: Bissengaliyeva, Mira R, Gogol, Daniil B, Bekturganov, Nuraly S, Taimassova, Shynar T, Bespyatov, Michael A, Zhusipov, Abdrazak A
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container_end_page 1945
container_issue 5
container_start_page 1941
container_title Journal of chemical and engineering data
container_volume 56
creator Bissengaliyeva, Mira R
Gogol, Daniil B
Bekturganov, Nuraly S
Taimassova, Shynar T
Bespyatov, Michael A
Zhusipov, Abdrazak A
description The heat capacity of natural lead molybdate (wulfenite, PbMoO4) has been measured by the method of vacuum adiabatic calorimetry over the temperature range of (4.3 to 80) K, and its thermodynamic functions in the range from (0 to 320) K have been calculated. The obtained standard values are as follows: C p o(298.15) = (119.4 ± 0.13) J·mol−1·K−1, S°(298.15) = (161.5 ± 0.3) J·mol−1·K−1, and ΔH°(298.15) = (23018 ± 23) J·mol−1. The experimental data have been compared with the calculated values of the heat capacity obtained previously by different methods. The greatest correspondence of the thermodynamic functions has been obtained when employing the method of interatomic potentials using the computer program LADY.
doi_str_mv 10.1021/je100950u
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The obtained standard values are as follows: C p o(298.15) = (119.4 ± 0.13) J·mol−1·K−1, S°(298.15) = (161.5 ± 0.3) J·mol−1·K−1, and ΔH°(298.15) = (23018 ± 23) J·mol−1. The experimental data have been compared with the calculated values of the heat capacity obtained previously by different methods. 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title Heat Capacity and Standard Thermodynamic Functions of the Wulfenite PbMoO4 over the Temperature Range of (0 to 320) K
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