Densities and ultrasonic studies for binary mixtures of tetrahydrofuran with chlorobenzenes, chlorotoluenes and nitrotoluenes at 298.15 K

• Published in: Fluid phase equilibria 2011-11, Vol.310 (1), p.74-81
• Main Authors: Madhusudhana Reddy, P., Siva kumar, K., Venkatesu, P.
• Format: Article
• Language: English
• Subjects: Chemical thermodynamics; Chemistry; Deviation in isentropic compressibility; Exact sciences and technology; Excess molar volumes; General and physical chemistry; Mixtures; Molecular interactions; Solvents; Thermodynamic properties; THF
• ISSN: 0378-3812; 1879-0224
• DOI: 10.1016/j.fluid.2011.07.018

► We report densities and sound velocities for THF with solvents. ► We have predicted V E and Δ κ s from measured ρ and u, respectively. ► Redlich–Kister polynomial was used to correlate the results. ► u data have been obtained in terms of FLT and CFT. ► The intermolecular interactions were analyzed on the basis of derived properties. Densities ( ρ) and ultrasonic sound velocities ( u) have been measured over the whole composition range for the binary mixtures of tetrahydrofuran (THF) with 1,2-dichlorobenzene (1,2-DCB), 1,3-dichlorobenzene (1,3-DCB), 1,2,4-trichlorobenzene (1,2,4-TCB), o-chlorotoluene ( o-CT), m-chlorotoluene ( m-CT), p-chlorotoluene ( p-CT), o-nitrotoluene ( o-NT) and m-nitrotoluene ( m-NT) at 298.15 K and atmospheric pressure. To gain some insight into the several aggregations of molecular interactions present in these mixed solvents, we determined the excess molar volume ( V E) and the deviation in isentropic compressibilities (Δ κ s) as a function of the concentration of THF from the measured ρ and u, respectively. The V E values have been correlated using Redlich–Kister and Hwang et al. equations. The V E data is completely positive over the entire mole fraction range in all the binary mixtures of THF with chlorobenzenes, chlorotoluenes and nitrotoluenes. The sound velocity data have been obtained in terms of free length theory (FLT) and collision factor theory (CFT). The Δ κ s values have been correlated using Redlich–Kister equation. The values of Δ κ s were negative over the entire composition range in all the binary mixtures under the same experimental conditions. The measured data were discussed on the basis of intermolecular interactions and structural effects between unlike molecules. Based on our V E data of THF + DCBs or TCB and THF + chlorotoluenes are compared with existing V E data of THF + chlorobenzene (CB) and THF + toluene (TE), respectively.