Synthesis of Diarylalkynes by Iron/Copper Co-Catalyzed Decarboxylative spsp2 Coupling of Alkynyl Carboxylic Acids and Aryl Halides

The highly effective decarboxylative sp‐sp2 coupling of alkynylcarboxylic acids with various aryl halides was carried in the presence of low‐cost and readily available copper(I) iodide/iron(III) acetylacetonate under ligand‐free and palladium‐free conditions using low catalyst loadings. This protoco...

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Published in:Advanced synthesis & catalysis 2011-10, Vol.353 (14-15), p.2731-2738
Main Authors: Li, Tingyi, Qu, Xiaoming, Zhu, Yan, Sun, Peng, Yang, Hailong, Shan, Yuqin, Zhang, Hongxin, Liu, Defu, Zhang, Xiang, Mao, Jincheng
Format: Article
Language:English
Subjects:
alkynylcarboxylic acids
aryl iodides
Chemistry
coupling reaction
decarboxylative reaction
diaryl- alkynes
Exact sciences and technology
Noncondensed benzenic compounds
Organic chemistry
Preparations and properties
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container_end_page 2738
container_issue 14-15
container_start_page 2731
container_title Advanced synthesis & catalysis
container_volume 353
creator Li, Tingyi
Qu, Xiaoming
Zhu, Yan
Sun, Peng
Yang, Hailong
Shan, Yuqin
Zhang, Hongxin
Liu, Defu
Zhang, Xiang
Mao, Jincheng
description The highly effective decarboxylative sp‐sp2 coupling of alkynylcarboxylic acids with various aryl halides was carried in the presence of low‐cost and readily available copper(I) iodide/iron(III) acetylacetonate under ligand‐free and palladium‐free conditions using low catalyst loadings. This protocol makes such coupling reactions more practical and useful.
doi_str_mv 10.1002/adsc.201100238
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subjects alkynylcarboxylic acids
aryl iodides
Chemistry
coupling reaction
decarboxylative reaction
diaryl- alkynes
Exact sciences and technology
Noncondensed benzenic compounds
Organic chemistry
Preparations and properties
title Synthesis of Diarylalkynes by Iron/Copper Co-Catalyzed Decarboxylative spsp2 Coupling of Alkynyl Carboxylic Acids and Aryl Halides
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