Trichloroethylene oxidation performance in sodium percarbonate (SPC)/Fe2+ system

• Published in: Environmental technology 2014-04, Vol.35 (7), p.791-798
• Main Authors: Zang, Xueke, Gu, Xiaogang, Lu, Shuguang, Qiu, Zhaofu, Sui, Qian, Lin, Kuangfei, Du, Xiaoming
• Format: Article
• Language: English
• Subjects: adverse effects; anions; Anions - chemistry; Applied sciences; Biological and physicochemical phenomena; carbon dioxide; Carbon Dioxide - chemistry; Carbonates - chemistry; Catalysis; catalytic; Catalytic reactions; Chemical engineering; Chemistry; Chlorine - chemistry; environmental technology; Exact sciences and technology; Ferrous Compounds - chemistry; General and physical chemistry; Groundwater; groundwater contamination; groundwater remediation; Groundwaters; humic acids; Humic Substances; Hydrocarbons - chemistry; Hydrogen-Ion Concentration; in-situ chemical oxidation (ISCO); Ions; iron; Iron - chemistry; Kinetics; Natural water pollution; oxidation; Oxygen - chemistry; Pollution; Reactors; remediation; sodium percarbonate; Solvents - chemistry; TCE; Temperature; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Time Factors; trichloroethylene; Trichloroethylene - chemistry; Water Pollutants, Chemical - chemistry; Water Purification - methods; Water treatment and pollution
• ISSN: 1479-487X; 0959-3330; 1479-487X
• DOI: 10.1080/09593330.2013.852592

In this study, in-situ chemical oxidation technique employing Fe(II) catalytic sodium percarbonate (SPC) to stimulate the oxidation of trichloroethylene (TCE) in contaminated groundwater remediation was investigated. The effects of various factors including the SPC/TCE/Fe ²⁺ molar ratio, the initial solution pH and the widely found constituents in groundwater matrix such as Cl ⁻, , and anions and natural organic matters were evaluated. The experimental results showed that TCE could be completely oxidized in 5 min at 20°C with a SPC/TCE/Fe ²⁺ molar ratio of 5:1:10, indicating the significant effectiveness of the SPC/Fe ²⁺ system for TCE removal. The initial solution pH value (from 3 to 11) has less influence on TCE oxidation rate. In contrast, Cl ⁻ and anions had a negative effect on TCE removal in which possesses a stronger influence than Cl ⁻, whereas the effects of both and anions appeared to be negligible. With the 1.0–10 mg/L concentrations of humic acid in solution, slightly inhibitive effect was observed, suggesting that dissolved organic matters consumed less SPC and had a negligible effect on the oxidation of TCE in SPC/Fe ²⁺ system. From the intermediate products’ analyses and the released Cl ⁻ contents from TCE parent contaminant in solution, all the decomposed TCE had completely dechlorinated and led to carbon dioxide and hydrocarbon. In conclusion, Fe(II) catalytic SPC oxidation is a highly promising technique for TCE-contaminated groundwater remediation, but some complex constituents such as , in in-situ groundwater matrix should be carefully considered for its practical application.