Measurement of Raman-Scattering Spectra of Rb2KMoO3F3 Crystal: Evidence for Controllable Disorder in the Lattice Structure

The λ-shaped line width broadening anomalies of octahedron group vibrations in Rb2KMoO3F3 disordered crystal have been revealed in the wide temperature range by Raman technique. The line width of Mo–O and Mo–F vibrations in this crystal is connected with the lattice disorder. The dependence of order...

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Bibliographic Details
Published in:Crystal growth & design 2014-03, Vol.14 (3), p.923-927
Main Authors: Krylov, A. S, Kolesnikova, E. M, Isaenko, L. I, Krylova, S. N, Vtyurin, A. N
Format: Article
Language:English
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Summary:The λ-shaped line width broadening anomalies of octahedron group vibrations in Rb2KMoO3F3 disordered crystal have been revealed in the wide temperature range by Raman technique. The line width of Mo–O and Mo–F vibrations in this crystal is connected with the lattice disorder. The dependence of ordering degree passing the phase transition point history has been discovered. Wide temperature–line width area is found below structural phase transition where different lattice disorder can be obtained at a given temperature by varying the rate of sample cooling. The current study demonstrates the ability of a dynamic temperature regime to control ordering processes in crystals.
ISSN:1528-7483
1528-7505
DOI:10.1021/cg4008894