Silylation de l'isoquinoléine: influence des conditions opératoires sur l'obtention de nouveaux hétérocycles siliciés

Silylation of isoquinoline with Me 3 SiCl/Li/THF or Me 3 SiCl/Mg/THF reagents has been studied. The choice of the metal and the experimental conditions govern the course of the silylation reaction and lead to new trimethylsilyl heterocyclic compounds.

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Bibliographic Details
Published in:Canadian journal of chemistry 1993-05, Vol.71 (5), p.754-761
Main Authors: Grignon-Dubois, Micheline, Fialeix, Michelle, Leger, Jean-Michel
Format: Article
Language:English
Subjects:
Chimie
Chimie organique
Composés hétérocycliques
Cycles à un atome n et leurs analogues condensés
Préparations et propriétés
Sciences exactes et technologie
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Description
Summary:Silylation of isoquinoline with Me 3 SiCl/Li/THF or Me 3 SiCl/Mg/THF reagents has been studied. The choice of the metal and the experimental conditions govern the course of the silylation reaction and lead to new trimethylsilyl heterocyclic compounds.
ISSN:0008-4042
1480-3291
DOI:10.1139/v93-099