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Triphenylsilyl perchlorate revisited: 29Si and 35Cl NMR spectroscopy and X-ray crystallography showing covalent nature in both solution and the solid state ― difficulties in observing long-lived silyl cations in the condensed state

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Published in:Journal of the American Chemical Society 1987, Vol.109 (17), p.5123-5126
Main Authors: SURYA PRAKASH, G. K, KEYANIYAN, S, ANISZFELD, R, HEILIGER, L, OLAH, G. A, STEVENS, R. C, HOK-KIN CHOI, BAU, R
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container_end_page 5126
container_issue 17
container_start_page 5123
container_title Journal of the American Chemical Society
container_volume 109
creator SURYA PRAKASH, G. K
KEYANIYAN, S
ANISZFELD, R
HEILIGER, L
OLAH, G. A
STEVENS, R. C
HOK-KIN CHOI
BAU, R
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ispartof Journal of the American Chemical Society, 1987, Vol.109 (17), p.5123-5126
issn 0002-7863
1520-5126
language eng
recordid cdi_pascalfrancis_primary_7714215
source ACS CRKN Legacy Archives
subjects Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Organic compounds
Organometalloidal and organometallic compounds
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
title Triphenylsilyl perchlorate revisited: 29Si and 35Cl NMR spectroscopy and X-ray crystallography showing covalent nature in both solution and the solid state ― difficulties in observing long-lived silyl cations in the condensed state
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