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Cation transport in gaseous nitrogen: density and temperature effects
The density-normalized mobility of nμ of cations in nitrogen gas at densities up to n c = 6.7 × 10 27 molecules/m 3 increases with temperature. At n ≤ 5.7 × 10 25 molecules/m 3 and T > 250 K, the dominating ion is N 4 + . At lower temperatures and higher densities, relatively loosely bound clu...
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| Published in: | Canadian journal of chemistry 1986-04, Vol.64 (4), p.777-779 |
|---|---|
| Main Authors: | , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that cite this one |
| Online Access: | Get full text |
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| cited_by | cdi_FETCH-LOGICAL-c320t-5849649061fc4f75e0451e1a79b991d8a806e776bda3bbd2c3c66c2adf3df7183 |
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| container_end_page | 779 |
| container_issue | 4 |
| container_start_page | 777 |
| container_title | Canadian journal of chemistry |
| container_volume | 64 |
| creator | Wada, Toshinori Gee, Norman Freeman, Gordon R |
| description | The density-normalized mobility of nμ of cations in nitrogen gas at densities up to n
c
= 6.7 × 10
27
molecules/m
3
increases with temperature. At n ≤ 5.7 × 10
25
molecules/m
3
and T > 250 K, the dominating ion is N
4
+
. At lower temperatures and higher densities, relatively loosely bound clusters N
4
+
(N
2
), N
4
+
(N
2
)
2
, ... form. Momentum transfer cross sections for N
4
+
-N
2
are governed at low energies by the polarization potential, and at high energies by the hard body potential. The cross section for N
2
+
-N
2
at high energies is larger than that for N
4
+
-N
2
. |
| doi_str_mv | 10.1139/v86-126 |
| format | article |
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c
= 6.7 × 10
27
molecules/m
3
increases with temperature. At n ≤ 5.7 × 10
25
molecules/m
3
and T > 250 K, the dominating ion is N
4
+
. At lower temperatures and higher densities, relatively loosely bound clusters N
4
+
(N
2
), N
4
+
(N
2
)
2
, ... form. Momentum transfer cross sections for N
4
+
-N
2
are governed at low energies by the polarization potential, and at high energies by the hard body potential. The cross section for N
2
+
-N
2
at high energies is larger than that for N
4
+
-N
2
.</description><identifier>ISSN: 0008-4042</identifier><identifier>EISSN: 1480-3291</identifier><identifier>DOI: 10.1139/v86-126</identifier><identifier>CODEN: CJCHAG</identifier><language>eng</language><publisher>Ottawa, Canada: NRC Research Press</publisher><subject>Exact sciences and technology ; Kinetic and transport theory of gases ; Physics ; Physics of gases ; Physics of gases, plasmas and electric discharges</subject><ispartof>Canadian journal of chemistry, 1986-04, Vol.64 (4), p.777-779</ispartof><rights>1987 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c320t-5849649061fc4f75e0451e1a79b991d8a806e776bda3bbd2c3c66c2adf3df7183</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=8075157$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Wada, Toshinori</creatorcontrib><creatorcontrib>Gee, Norman</creatorcontrib><creatorcontrib>Freeman, Gordon R</creatorcontrib><title>Cation transport in gaseous nitrogen: density and temperature effects</title><title>Canadian journal of chemistry</title><addtitle>Revue canadienne de chimie</addtitle><description>The density-normalized mobility of nμ of cations in nitrogen gas at densities up to n
c
= 6.7 × 10
27
molecules/m
3
increases with temperature. At n ≤ 5.7 × 10
25
molecules/m
3
and T > 250 K, the dominating ion is N
4
+
. At lower temperatures and higher densities, relatively loosely bound clusters N
4
+
(N
2
), N
4
+
(N
2
)
2
, ... form. Momentum transfer cross sections for N
4
+
-N
2
are governed at low energies by the polarization potential, and at high energies by the hard body potential. The cross section for N
2
+
-N
2
at high energies is larger than that for N
4
+
-N
2
.</description><subject>Exact sciences and technology</subject><subject>Kinetic and transport theory of gases</subject><subject>Physics</subject><subject>Physics of gases</subject><subject>Physics of gases, plasmas and electric discharges</subject><issn>0008-4042</issn><issn>1480-3291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1986</creationdate><recordtype>article</recordtype><recordid>eNp9z01LAzEQgOEgCtYq_oUcREFYzdcmWW9S6gcUvOh5ySaTutJmlyQV-u8bafGmp2HgYZgXoUtK7ijlzf23lhVl8ghNqNCk4qyhx2hCCNGVIIKdorOUvsqqCKsnaD4zuR8CztGENA4x4z7gpUkwbBIOfY7DEsIDdhBSn7fYBIczrEeIJm8iYPAebE7n6MSbVYKLw5yij6f5--ylWrw9v84eF5XljOSq1qKRoiGSeiu8qoGImgI1qumahjptNJGglOyc4V3nmOVWSsuM89x5RTWfopv9XRuHlCL4doz92sRtS0n7U9-W-rbUF3m1l6NJ1qx8ybN9-uWaqJrWqrDbPQvRRkhgov385-b13_iA2rE8uwO1dHV6</recordid><startdate>19860401</startdate><enddate>19860401</enddate><creator>Wada, Toshinori</creator><creator>Gee, Norman</creator><creator>Freeman, Gordon R</creator><general>NRC Research Press</general><general>National Research Council of Canada</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19860401</creationdate><title>Cation transport in gaseous nitrogen: density and temperature effects</title><author>Wada, Toshinori ; Gee, Norman ; Freeman, Gordon R</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c320t-5849649061fc4f75e0451e1a79b991d8a806e776bda3bbd2c3c66c2adf3df7183</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1986</creationdate><topic>Exact sciences and technology</topic><topic>Kinetic and transport theory of gases</topic><topic>Physics</topic><topic>Physics of gases</topic><topic>Physics of gases, plasmas and electric discharges</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wada, Toshinori</creatorcontrib><creatorcontrib>Gee, Norman</creatorcontrib><creatorcontrib>Freeman, Gordon R</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Canadian journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wada, Toshinori</au><au>Gee, Norman</au><au>Freeman, Gordon R</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cation transport in gaseous nitrogen: density and temperature effects</atitle><jtitle>Canadian journal of chemistry</jtitle><addtitle>Revue canadienne de chimie</addtitle><date>1986-04-01</date><risdate>1986</risdate><volume>64</volume><issue>4</issue><spage>777</spage><epage>779</epage><pages>777-779</pages><issn>0008-4042</issn><eissn>1480-3291</eissn><coden>CJCHAG</coden><abstract>The density-normalized mobility of nμ of cations in nitrogen gas at densities up to n
c
= 6.7 × 10
27
molecules/m
3
increases with temperature. At n ≤ 5.7 × 10
25
molecules/m
3
and T > 250 K, the dominating ion is N
4
+
. At lower temperatures and higher densities, relatively loosely bound clusters N
4
+
(N
2
), N
4
+
(N
2
)
2
, ... form. Momentum transfer cross sections for N
4
+
-N
2
are governed at low energies by the polarization potential, and at high energies by the hard body potential. The cross section for N
2
+
-N
2
at high energies is larger than that for N
4
+
-N
2
.</abstract><cop>Ottawa, Canada</cop><pub>NRC Research Press</pub><doi>10.1139/v86-126</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0008-4042 |
| ispartof | Canadian journal of chemistry, 1986-04, Vol.64 (4), p.777-779 |
| issn | 0008-4042 1480-3291 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_8075157 |
| source | EZB Electronic Journals Library |
| subjects | Exact sciences and technology Kinetic and transport theory of gases Physics Physics of gases Physics of gases, plasmas and electric discharges |
| title | Cation transport in gaseous nitrogen: density and temperature effects |
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