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Bromoform Formation in Ozonated Groundwater Containing Bromide and Humic Substances
The effect of bromide ion, organic carbon concentration (natural aquatic humic substances), pH, and solar irradiation on the formation of bromoform in ozonated groundwater has been studied. The studies were conducted on four unique samples of groundwater taken from different regions of the Biscayne...
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| Published in: | Ozone: science & engineering 1986-01, Vol.8 (1), p.63-75 |
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| Main Authors: | , , , |
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| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c449t-4d846fa9d0659f4b8e0353aa5840b0f008cd282ceee980ec116990ec5268dfca3 |
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| cites | cdi_FETCH-LOGICAL-c449t-4d846fa9d0659f4b8e0353aa5840b0f008cd282ceee980ec116990ec5268dfca3 |
| container_end_page | 75 |
| container_issue | 1 |
| container_start_page | 63 |
| container_title | Ozone: science & engineering |
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| creator | Cooper, William J. Amy, Gary L. Moore, Cynthia A. Zilca, Rod G. |
| description | The effect of bromide ion, organic carbon concentration (natural aquatic humic substances), pH, and solar irradiation on the formation of bromoform in ozonated groundwater has been studied. The studies were conducted on four unique samples of groundwater taken from different regions of the Biscayne Aquifer in southern Florida. All other conditions being equal, increases in bromide ion concentrations resulted in increases in CHBrg formation. In three of the four samples, CHBr
3
formation decreased as the pH level increased from 5 to 9. The fourth sample exhibited an opposite trend whereby the CHBr
3
concentration increased with increasing pH. Bromoform concentration increased with increased O
3
concentration over an ozone dosage range of 3.4 to 6.7 mg/L. |
| doi_str_mv | 10.1080/01919518608552304 |
| format | article |
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3
formation decreased as the pH level increased from 5 to 9. The fourth sample exhibited an opposite trend whereby the CHBr
3
concentration increased with increasing pH. Bromoform concentration increased with increased O
3
concentration over an ozone dosage range of 3.4 to 6.7 mg/L.</description><identifier>ISSN: 0191-9512</identifier><identifier>EISSN: 1547-6545</identifier><identifier>DOI: 10.1080/01919518608552304</identifier><identifier>CODEN: OZSEDS</identifier><language>eng</language><publisher>Philadelphia, PA: Taylor & Francis Group</publisher><subject>400500 - Photochemistry ; Applied sciences ; Bromate Ion ; Bromide Ion ; BROMINATED ALIPHATIC HYDROCARBONS ; BROMINATION ; BROMOFORM ; CHEMICAL REACTION YIELD ; CHEMICAL REACTIONS ; CHEMISTRY ; Exact sciences and technology ; GROUND WATER ; Groundwaters ; HALOGENATED ALIPHATIC HYDROCARBONS ; HALOGENATION ; HUMIC ACIDS ; Humic Substances ; HYDROGEN COMPOUNDS ; Hypobromite Ion ; Hypobromous Acid ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; Natural water pollution ; ORGANIC ACIDS ; ORGANIC BROMINE COMPOUNDS ; Organic Carbon ; ORGANIC COMPOUNDS ; ORGANIC HALOGEN COMPOUNDS ; Organo-Bromine Compounds ; OXYGEN COMPOUNDS ; Ozonated Groundwater ; OZONIZATION ; PH VALUE ; PHOTOCHEMISTRY ; Photodecomposition of HOBr/OBr ; Pollution ; WATER ; Water treatment and pollution ; YIELDS</subject><ispartof>Ozone: science & engineering, 1986-01, Vol.8 (1), p.63-75</ispartof><rights>Copyright Taylor & Francis Group, LLC 1986</rights><rights>1986 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c449t-4d846fa9d0659f4b8e0353aa5840b0f008cd282ceee980ec116990ec5268dfca3</citedby><cites>FETCH-LOGICAL-c449t-4d846fa9d0659f4b8e0353aa5840b0f008cd282ceee980ec116990ec5268dfca3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/01919518608552304$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/01919518608552304$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,780,784,885,4024,27923,27924,27925,59901,60690</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=8708685$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5910999$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Cooper, William J.</creatorcontrib><creatorcontrib>Amy, Gary L.</creatorcontrib><creatorcontrib>Moore, Cynthia A.</creatorcontrib><creatorcontrib>Zilca, Rod G.</creatorcontrib><title>Bromoform Formation in Ozonated Groundwater Containing Bromide and Humic Substances</title><title>Ozone: science & engineering</title><description>The effect of bromide ion, organic carbon concentration (natural aquatic humic substances), pH, and solar irradiation on the formation of bromoform in ozonated groundwater has been studied. The studies were conducted on four unique samples of groundwater taken from different regions of the Biscayne Aquifer in southern Florida. All other conditions being equal, increases in bromide ion concentrations resulted in increases in CHBrg formation. In three of the four samples, CHBr
3
formation decreased as the pH level increased from 5 to 9. The fourth sample exhibited an opposite trend whereby the CHBr
3
concentration increased with increasing pH. Bromoform concentration increased with increased O
3
concentration over an ozone dosage range of 3.4 to 6.7 mg/L.</description><subject>400500 - Photochemistry</subject><subject>Applied sciences</subject><subject>Bromate Ion</subject><subject>Bromide Ion</subject><subject>BROMINATED ALIPHATIC HYDROCARBONS</subject><subject>BROMINATION</subject><subject>BROMOFORM</subject><subject>CHEMICAL REACTION YIELD</subject><subject>CHEMICAL REACTIONS</subject><subject>CHEMISTRY</subject><subject>Exact sciences and technology</subject><subject>GROUND WATER</subject><subject>Groundwaters</subject><subject>HALOGENATED ALIPHATIC HYDROCARBONS</subject><subject>HALOGENATION</subject><subject>HUMIC ACIDS</subject><subject>Humic Substances</subject><subject>HYDROGEN COMPOUNDS</subject><subject>Hypobromite Ion</subject><subject>Hypobromous Acid</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>Natural water pollution</subject><subject>ORGANIC ACIDS</subject><subject>ORGANIC BROMINE COMPOUNDS</subject><subject>Organic Carbon</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC HALOGEN COMPOUNDS</subject><subject>Organo-Bromine Compounds</subject><subject>OXYGEN COMPOUNDS</subject><subject>Ozonated Groundwater</subject><subject>OZONIZATION</subject><subject>PH VALUE</subject><subject>PHOTOCHEMISTRY</subject><subject>Photodecomposition of HOBr/OBr</subject><subject>Pollution</subject><subject>WATER</subject><subject>Water treatment and pollution</subject><subject>YIELDS</subject><issn>0191-9512</issn><issn>1547-6545</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1986</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LAzEQhoMoWD9-gLcg4m11sptsE_CixS8o9KCeQ5pkNbKbaJJF6q83pepFvMw7MM87w7wIHRE4I8DhHIggghHeAmesboBuoQlhdFq1jLJtNFnPqwLUu2gvpVeAuiaET9DDVQxD6EIc8E0pKrvgsfN48Rm8ytbg2xhGbz5KH_Es-Kycd_4Zr23OWKy8wXfj4DR-GJcpK69tOkA7neqTPfzWffR0c_04u6vmi9v72eW80pSKXFHDadspYaBloqNLbqFhjVKMU1hCB8C1qXmtrbWCg9WEtEIUZXXLTadVs4-ON3tDyk4m7bLVLzp4b3WWTBAQQhTodAO9xfA-2pTl4JK2fa-8DWOSpOElCD4tINmAOoaUou3kW3SDiitJQK4zln8yLp6T7-UqadV3sfzv0q-RT4G3nBXsYoM5v05afYTYG5nVqg_xx9P8f-UL-3eOKQ</recordid><startdate>19860101</startdate><enddate>19860101</enddate><creator>Cooper, William J.</creator><creator>Amy, Gary L.</creator><creator>Moore, Cynthia A.</creator><creator>Zilca, Rod G.</creator><general>Taylor & Francis Group</general><general>Taylor & Francis</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>OTOTI</scope></search><sort><creationdate>19860101</creationdate><title>Bromoform Formation in Ozonated Groundwater Containing Bromide and Humic Substances</title><author>Cooper, William J. ; Amy, Gary L. ; Moore, Cynthia A. ; Zilca, Rod G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c449t-4d846fa9d0659f4b8e0353aa5840b0f008cd282ceee980ec116990ec5268dfca3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1986</creationdate><topic>400500 - Photochemistry</topic><topic>Applied sciences</topic><topic>Bromate Ion</topic><topic>Bromide Ion</topic><topic>BROMINATED ALIPHATIC HYDROCARBONS</topic><topic>BROMINATION</topic><topic>BROMOFORM</topic><topic>CHEMICAL REACTION YIELD</topic><topic>CHEMICAL REACTIONS</topic><topic>CHEMISTRY</topic><topic>Exact sciences and technology</topic><topic>GROUND WATER</topic><topic>Groundwaters</topic><topic>HALOGENATED ALIPHATIC HYDROCARBONS</topic><topic>HALOGENATION</topic><topic>HUMIC ACIDS</topic><topic>Humic Substances</topic><topic>HYDROGEN COMPOUNDS</topic><topic>Hypobromite Ion</topic><topic>Hypobromous Acid</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>Natural water pollution</topic><topic>ORGANIC ACIDS</topic><topic>ORGANIC BROMINE COMPOUNDS</topic><topic>Organic Carbon</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC HALOGEN COMPOUNDS</topic><topic>Organo-Bromine Compounds</topic><topic>OXYGEN COMPOUNDS</topic><topic>Ozonated Groundwater</topic><topic>OZONIZATION</topic><topic>PH VALUE</topic><topic>PHOTOCHEMISTRY</topic><topic>Photodecomposition of HOBr/OBr</topic><topic>Pollution</topic><topic>WATER</topic><topic>Water treatment and pollution</topic><topic>YIELDS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cooper, William J.</creatorcontrib><creatorcontrib>Amy, Gary L.</creatorcontrib><creatorcontrib>Moore, Cynthia A.</creatorcontrib><creatorcontrib>Zilca, Rod G.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>OSTI.GOV</collection><jtitle>Ozone: science & engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cooper, William J.</au><au>Amy, Gary L.</au><au>Moore, Cynthia A.</au><au>Zilca, Rod G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bromoform Formation in Ozonated Groundwater Containing Bromide and Humic Substances</atitle><jtitle>Ozone: science & engineering</jtitle><date>1986-01-01</date><risdate>1986</risdate><volume>8</volume><issue>1</issue><spage>63</spage><epage>75</epage><pages>63-75</pages><issn>0191-9512</issn><eissn>1547-6545</eissn><coden>OZSEDS</coden><abstract>The effect of bromide ion, organic carbon concentration (natural aquatic humic substances), pH, and solar irradiation on the formation of bromoform in ozonated groundwater has been studied. The studies were conducted on four unique samples of groundwater taken from different regions of the Biscayne Aquifer in southern Florida. All other conditions being equal, increases in bromide ion concentrations resulted in increases in CHBrg formation. In three of the four samples, CHBr
3
formation decreased as the pH level increased from 5 to 9. The fourth sample exhibited an opposite trend whereby the CHBr
3
concentration increased with increasing pH. Bromoform concentration increased with increased O
3
concentration over an ozone dosage range of 3.4 to 6.7 mg/L.</abstract><cop>Philadelphia, PA</cop><pub>Taylor & Francis Group</pub><doi>10.1080/01919518608552304</doi><tpages>13</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0191-9512 |
| ispartof | Ozone: science & engineering, 1986-01, Vol.8 (1), p.63-75 |
| issn | 0191-9512 1547-6545 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_8708685 |
| source | Taylor & Francis Engineering, Computing & Technology Archive |
| subjects | 400500 - Photochemistry Applied sciences Bromate Ion Bromide Ion BROMINATED ALIPHATIC HYDROCARBONS BROMINATION BROMOFORM CHEMICAL REACTION YIELD CHEMICAL REACTIONS CHEMISTRY Exact sciences and technology GROUND WATER Groundwaters HALOGENATED ALIPHATIC HYDROCARBONS HALOGENATION HUMIC ACIDS Humic Substances HYDROGEN COMPOUNDS Hypobromite Ion Hypobromous Acid INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Natural water pollution ORGANIC ACIDS ORGANIC BROMINE COMPOUNDS Organic Carbon ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS Organo-Bromine Compounds OXYGEN COMPOUNDS Ozonated Groundwater OZONIZATION PH VALUE PHOTOCHEMISTRY Photodecomposition of HOBr/OBr Pollution WATER Water treatment and pollution YIELDS |
| title | Bromoform Formation in Ozonated Groundwater Containing Bromide and Humic Substances |
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