Comparative studies of the pyrolytic and kinetic characteristics of maize straw and the seaweed Ulva pertusa

• Published in: PloS one 2010-09, Vol.5 (9), p.e12641
• Main Authors: Ye, Naihao, Li, Demao, Chen, Limei, Zhang, Xiaowen, Xu, Dong
• Format: Article
• Language: English
• Subjects: Activation energy; Algae; Biodiesel fuels; Biofuels; Biomass; Biomass energy; Biotechnology/Bioengineering; Cellulose; Chemistry/Applied Chemistry; Chlorophyta; Comparative studies; Corn; Corn straw; Decomposition; Dehydration; Devolatilization; Fishery sciences; Food science; Hot Temperature; Integrated approach; Kinetics; Laboratories; Marine and Aquatic Sciences; Oryza; Petroleum production; Pinus; Plant Stems - chemistry; Pyrolysis; Raw materials; Straw; Studies; Test methods; Thermal stability; Ulva - chemistry; Ulva pertusa; Zea mays; Zea mays - chemistry
• ISSN: 1932-6203; 1932-6203
• DOI: 10.1371/journal.pone.0012641

Seaweed has attracted considerable attention as a potential biofuel feedstock. The pyrolytic and kinetic characteristics of maize straw and the seaweed Ulva pertusa were studied and compared using heating rates of 10, 30 and 50°C min(-1) under an inert atmosphere. The activation energy, and pre-exponential factors were calculated by the Flynn-Wall-Ozawa (FWO), Kissinger-Akahira-Sunose (KAS) and Popescu methods. The kinetic mechanism was deduced by the Popescu method. The results indicate that there are three stages to the pyrolysis; dehydration, primary devolatilization and residual decomposition. There were significant differences in average activation energy, thermal stability, final residuals and reaction rates between the two materials. The primary devolatilization stage of U. pertusa can be described by the Avramic-Erofeev equation (n=3), whereas that of maize straw can be described by the Mampel Power Law (n=2). The average activation energy of maize straw and U. pertusa were 153.0 and 148.7 KJ mol(-1), respectively. The pyrolysis process of U.pertusa would be easier than maize straw. And co-firing of the two biomass may be require less external heat input and improve process stability. There were minor kinetic compensation effects between the pre-exponential factors and the activation energy.