Evaluating status change of soil potassium from path model

• Published in: PloS one 2013, Vol.8 (10), p.e76712-e76712
• Main Authors: He, Wenming, Chen, Fang
• Format: Article
• Language: English
• Subjects: Adsorption; Agricultural practices; Agriculture - methods; Carbon - analysis; Carbonates; Carbonates - analysis; Ecology; Efficiency; Environmental parameters; Equilibrium; Experiments; Fertilization; Genotype & phenotype; Humic Substances - analysis; Hydrogen-Ion Concentration; Laboratories; Magnesium - analysis; Mathematical models; Models, Theoretical; Nitrogen - analysis; Nutrition; Organic matter; Organic soils; pH effects; Phosphorus; Poaceae - growth & development; Potassium; Potassium - analysis; Potassium - chemistry; Rhizosphere; Science; Sodium; Sodium - analysis; Soil - chemistry; Soil investigations; Soil organic matter; Soil properties; Soil sciences; Soil solution; Soil treatment; Soil water; Solubility; Studies; Sulfur - analysis; Water chemistry; Water shortages; Water treatment
• ISSN: 1932-6203; 1932-6203
• DOI: 10.1371/journal.pone.0076712

The purpose of this study is to determine critical environmental parameters of soil K availability and to quantify those contributors by using a proposed path model. In this study, plot experiments were designed into different treatments, and soil samples were collected and further analyzed in laboratory to investigate soil properties influence on soil potassium forms (water soluble K, exchangeable K, non-exchangeable K). Furthermore, path analysis based on proposed path model was carried out to evaluate the relationship between potassium forms and soil properties. Research findings were achieved as followings. Firstly, key direct factors were soil S, ratio of sodium-potassium (Na/K), the chemical index of alteration (CIA), Soil Organic Matter in soil solution (SOM), Na and total nitrogen in soil solution (TN), and key indirect factors were Carbonate (CO3), Mg, pH, Na, S, and SOM. Secondly, path model can effectively determine direction and quantities of potassium status changes between Exchangeable potassium (eK), Non-exchangeable potassium (neK) and water-soluble potassium (wsK) under influences of specific environmental parameters. In reversible equilibrium state of [Formula: see text], K balance state was inclined to be moved into β and χ directions in treatments of potassium shortage. However in reversible equilibrium of [Formula: see text], K balance state was inclined to be moved into θ and λ directions in treatments of water shortage. Results showed that the proposed path model was able to quantitatively disclose moving direction of K status and quantify its equilibrium threshold. It provided a theoretical and practical basis for scientific and effective fertilization in agricultural plants growth.