Haze particles over a coal-burning region in the China Loess Plateau in winter: Three flight missions in December 2010

• Published in: Journal of Geophysical Research: Atmospheres 2012-06, Vol.117 (D12), p.n/a
• Main Authors: Li, Weijun, Shi, Zongbo, Zhang, Daizhou, Zhang, Xiaoye, Li, Peiren, Feng, Qiujuan, Yuan, Qi, Wang, Wenxing
• Format: Article
• Language: English
• Subjects: Aerosols; Anthropogenic factors; Atmospheric aerosols; Atmospheric sciences; brown haze; Coal; coal burning; Earth sciences; Earth, ocean, space; Emissions; Exact sciences and technology; Fly ash; Geophysics; Haze; individual aerosol particle; SO2; Sulfates; Sulfur dioxide; Troposphere; Water vapor
• ISSN: 0148-0227; 2169-897X; 2156-2202; 2169-8996
• DOI: 10.1029/2012JD017720

Heavy haze frequently occurs in winter over a coal‐burning region, the Taiyuan Basin, in the eastern China Loess Plateau, which is the upstream area of the North China Plain. We participated in three research flights to collect aerosol particles and to monitor SO2concentration in hazes from the ground (780 m asl) up to ∼4000 m during 17–18 December, 2010. Meteorological records reveal that the whole haze column (ground to 4000 m) was stable and could be further divided into three sub‐layers depending on the sampling altitude, which are characterized by two shifts of the lapse rate of virtual potential temperature and water vapor mixing ratio: Layer‐1, surface to 1500 m; Layer‐2, 1500 ∼ 3000 m on 17 December, and 1500 ∼ 2500 m on 18 December; Layer‐3, above 3000 m on 17 December and above 2500 m on 18 December. SO2concentration was 16–116 ppb with an average of 58 ppb in the Layer‐1, 2–45 ppb with an average of 10 ppb in the Layer‐2, and 1–10 ppb with an average of 4 ppb in the Layer‐3. The accumulation of SO2in the Layer‐1 was due to the stable meteorological conditions and the strong anthropogenic emissions in addition to the possible valley topography. Analyses of the collected particles using a transmission electron microscope revealed the dominance of organic particles and fly ash in the Layer‐1 and Layer‐2 and sulfate particles in the Layer‐3. The organic aerosols frequently contained certain amounts of Si and Cl. Fly ash particles consisted of O and Si with minor Fe, Mn, Zn, Ti, Pb, As, Co, and Cr. These two types of aerosol particles are typically emitted from coal burning. These results indicate that the haze particles were characterized in principle by aerosols from primary emissions of coal burning, which are different from those over the North China Plain where secondary sulfate particles are the dominant component. Key Points Aircraft was employed to understand compositions and sources of haze aerosols The hazes were mainly formed as a result of the primary coal burning emissions The SO2 mixing ratios of 8 to 12 ppb above 1500 m are greater than other places