Preparation and properties of NBR composites filled with a novel black liquor-montmorillonite complex

A novel rubber filler, black liquor–montmorillonite complex (BL–MMT) was prepared by dehydration of a mixture of MMT and BL and used in the preparation of acrylonitrile butadiene rubber (NBR) composites by mechanical mixing method. The BL–MMT/rubber composites were characterized using X‐ray diffract...

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Bibliographic Details
Published in:Journal of applied polymer science 2013-03, Vol.127 (5), p.3725-3730
Main Authors: Cao, Zhonglin, Liao, Zedong, Wang, Xi, Su, Shengpei, Feng, Jianxiang, Zhu, Jin
Format: Article
Language:English
Subjects:
Applied sciences
black liquor
Composites
Exact sciences and technology
Forms of application and semi-finished materials
Materials science
montmorillonite
NBR composites
Polymer industry, paints, wood
Polymers
Technology of polymers
thermal properties
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Summary:A novel rubber filler, black liquor–montmorillonite complex (BL–MMT) was prepared by dehydration of a mixture of MMT and BL and used in the preparation of acrylonitrile butadiene rubber (NBR) composites by mechanical mixing method. The BL–MMT/rubber composites were characterized using X‐ray diffraction (XRD), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and differential scanning calorimeter (DSC). Experimental results of XRD and TEM indicated that MMT was well‐dispersed in the rubber because of the presence of lignin. DSC, thermo‐oxidative aging measurements and TGA results demonstrated that the thermal properties of NBR were improved due to the addition of BL–MMT. The tensile properties including tensile strength, elongation at break, and modulus were also tested. All experimental results indicated that this BL–MMT complex could be an effective reinforcing agent in rubber for cost‐saving and environment benefits. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
ISSN:0021-8995
1097-4628
DOI:10.1002/app.37984