3d Metal Ions in Highly Unusual Eight-Coordination: The Phosphate-Capped Dodecapalladate(II) Nanocube

Trapped in a noble cube: A novel family of noble metalates has been discovered in which a 3d metal ion M (M = Mn(II), Fe(III), Co(II), Cu(II), Zn(II)) is encapsulated by a 12 palladium-oxo cage {Pd(12)O(32)}, which is capped by eight phosphate groups. Such discrete nanocubes were further investigate...

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Bibliographic Details
Published in:Chemistry : a European journal 2012-05, Vol.18 (20), p.6167
Main Authors: Barsukova-Stuckart, Maria, Izarova, Natalya V, Barrett, Ryan, Wang, Zhenxing, vanTol, Johan, Kroto, Harold W, Dalal, Naresh S, Keita, Bineta, Heller, Detlef, Kortz, Ulrich
Format: Article
Language:English
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Chemistry
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Summary:Trapped in a noble cube: A novel family of noble metalates has been discovered in which a 3d metal ion M (M = Mn(II), Fe(III), Co(II), Cu(II), Zn(II)) is encapsulated by a 12 palladium-oxo cage {Pd(12)O(32)}, which is capped by eight phosphate groups. Such discrete nanocubes were further investigated by EPR spectroscopy, electrochemistry, and in homogeneous hydrogenation catalysis.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201200060