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A new linear trinuclear cobalt complex bearing oximato and azido ligands: synthesis, structure, and magnetic characterization
The reaction of CoCl 2 · 6H 2 O, mpkoH (methyl 2-pyridyl ketone oxime), NEt 3 , and NaN 3 in a 1 : 1 : 2 : 1 molar ratio affords a linear trinuclear complex, [ Co II (mpko) 4 (N 3 ) 4 (H 2 O) 2 ] (1). Complex 1 has been characterized by single-crystal X-ray diffraction, elemental analysis, and infr...
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| Published in: | Journal of coordination chemistry 2012-09, Vol.65 (18), p.3308-3315 |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c368t-5831331a0b2e514265d47d67e7611c370b34ff9d0b04e68e151b9825086d90d43 |
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| cites | cdi_FETCH-LOGICAL-c368t-5831331a0b2e514265d47d67e7611c370b34ff9d0b04e68e151b9825086d90d43 |
| container_end_page | 3315 |
| container_issue | 18 |
| container_start_page | 3308 |
| container_title | Journal of coordination chemistry |
| container_volume | 65 |
| creator | Qiu, Xiu-Min Wang, Su-Na Lu, Jing Kong, Ling-Qian Li, Da-Cheng Dou, Jian-Min |
| description | The reaction of CoCl
2
· 6H
2
O, mpkoH (methyl 2-pyridyl ketone oxime), NEt
3
, and NaN
3
in a 1 : 1 : 2 : 1 molar ratio affords a linear trinuclear complex, [
Co
II
(mpko)
4
(N
3
)
4
(H
2
O)
2
] (1). Complex 1 has been characterized by single-crystal X-ray diffraction, elemental analysis, and infrared spectrum. Three cobalt ions are in the center of distorted octahedra, which are connected by two μ-1,1 azides and two oxime oxygen atoms to form a linear trinuclear structure. Discrete units of 1 are connected to form a stable 3-D supramolecular network by C-H···O and C-H···N weak interactions. Variable temperature magnetic susceptibility measurements reveal that 1 exhibits antiferromagnetic behavior. |
| doi_str_mv | 10.1080/00958972.2012.703779 |
| format | article |
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2
· 6H
2
O, mpkoH (methyl 2-pyridyl ketone oxime), NEt
3
, and NaN
3
in a 1 : 1 : 2 : 1 molar ratio affords a linear trinuclear complex, [
Co
II
(mpko)
4
(N
3
)
4
(H
2
O)
2
] (1). Complex 1 has been characterized by single-crystal X-ray diffraction, elemental analysis, and infrared spectrum. Three cobalt ions are in the center of distorted octahedra, which are connected by two μ-1,1 azides and two oxime oxygen atoms to form a linear trinuclear structure. Discrete units of 1 are connected to form a stable 3-D supramolecular network by C-H···O and C-H···N weak interactions. Variable temperature magnetic susceptibility measurements reveal that 1 exhibits antiferromagnetic behavior.</description><identifier>ISSN: 0095-8972</identifier><identifier>EISSN: 1029-0389</identifier><identifier>DOI: 10.1080/00958972.2012.703779</identifier><language>eng</language><publisher>Abingdon: Taylor & Francis Group</publisher><subject>Cobalt ; Cobalt complex ; Crystal structure ; Diffraction ; Distortion ; Ligands ; Magnetic permeability ; Magnetic properties ; Mineralogy ; Networks ; Oxime ; Oximes ; Three dimensional</subject><ispartof>Journal of coordination chemistry, 2012-09, Vol.65 (18), p.3308-3315</ispartof><rights>Copyright Taylor & Francis Group, LLC 2012</rights><rights>Copyright Taylor and Francis Group, LLC</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c368t-5831331a0b2e514265d47d67e7611c370b34ff9d0b04e68e151b9825086d90d43</citedby><cites>FETCH-LOGICAL-c368t-5831331a0b2e514265d47d67e7611c370b34ff9d0b04e68e151b9825086d90d43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27900,27901</link.rule.ids></links><search><creatorcontrib>Qiu, Xiu-Min</creatorcontrib><creatorcontrib>Wang, Su-Na</creatorcontrib><creatorcontrib>Lu, Jing</creatorcontrib><creatorcontrib>Kong, Ling-Qian</creatorcontrib><creatorcontrib>Li, Da-Cheng</creatorcontrib><creatorcontrib>Dou, Jian-Min</creatorcontrib><title>A new linear trinuclear cobalt complex bearing oximato and azido ligands: synthesis, structure, and magnetic characterization</title><title>Journal of coordination chemistry</title><description>The reaction of CoCl
2
· 6H
2
O, mpkoH (methyl 2-pyridyl ketone oxime), NEt
3
, and NaN
3
in a 1 : 1 : 2 : 1 molar ratio affords a linear trinuclear complex, [
Co
II
(mpko)
4
(N
3
)
4
(H
2
O)
2
] (1). Complex 1 has been characterized by single-crystal X-ray diffraction, elemental analysis, and infrared spectrum. Three cobalt ions are in the center of distorted octahedra, which are connected by two μ-1,1 azides and two oxime oxygen atoms to form a linear trinuclear structure. Discrete units of 1 are connected to form a stable 3-D supramolecular network by C-H···O and C-H···N weak interactions. Variable temperature magnetic susceptibility measurements reveal that 1 exhibits antiferromagnetic behavior.</description><subject>Cobalt</subject><subject>Cobalt complex</subject><subject>Crystal structure</subject><subject>Diffraction</subject><subject>Distortion</subject><subject>Ligands</subject><subject>Magnetic permeability</subject><subject>Magnetic properties</subject><subject>Mineralogy</subject><subject>Networks</subject><subject>Oxime</subject><subject>Oximes</subject><subject>Three dimensional</subject><issn>0095-8972</issn><issn>1029-0389</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp9kU9rFTEUxYMo-Gz9Bi4Cblx0njfJTDJxI6W0KhS6adchk8m8pmSSZ5KhfYV-dzM-3bhwdf_wO5fDPQh9ILAl0MNnANn1UtAtBUK3ApgQ8hXaEKCyAdbL12izIs3KvEXvcn4AIIxRsUEv5zjYR-xdsDrhklxYjF9bEwftSy3z3tsnPNSdCzscn9ysS8Q6jFg_uzFW6a4O-QvOh1DubXb5DOeSFlOWZM9-g7PeBVucweZeJ22KTe5ZFxfDKXozaZ_t-z_1BN1dXd5efG-ub779uDi_bgzjfWm6nlW7RMNAbUdayruxFSMXVnBCDBMwsHaa5AgDtJb3lnRkkD3toOejhLFlJ-jT8e4-xZ-LzUXNLhvrvQ42LlmRltXXSC66in78B32ISwrVnSK0hY4L3tFKtUfKpJhzspPap_qYdFAE1JqJ-puJWjNRx0yq7OtR5sIU06wfY_KjKvrgY5qSDsZlxf574Rff-pMa</recordid><startdate>20120920</startdate><enddate>20120920</enddate><creator>Qiu, Xiu-Min</creator><creator>Wang, Su-Na</creator><creator>Lu, Jing</creator><creator>Kong, Ling-Qian</creator><creator>Li, Da-Cheng</creator><creator>Dou, Jian-Min</creator><general>Taylor & Francis Group</general><general>Taylor & Francis Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20120920</creationdate><title>A new linear trinuclear cobalt complex bearing oximato and azido ligands: synthesis, structure, and magnetic characterization</title><author>Qiu, Xiu-Min ; Wang, Su-Na ; Lu, Jing ; Kong, Ling-Qian ; Li, Da-Cheng ; Dou, Jian-Min</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c368t-5831331a0b2e514265d47d67e7611c370b34ff9d0b04e68e151b9825086d90d43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Cobalt</topic><topic>Cobalt complex</topic><topic>Crystal structure</topic><topic>Diffraction</topic><topic>Distortion</topic><topic>Ligands</topic><topic>Magnetic permeability</topic><topic>Magnetic properties</topic><topic>Mineralogy</topic><topic>Networks</topic><topic>Oxime</topic><topic>Oximes</topic><topic>Three dimensional</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Qiu, Xiu-Min</creatorcontrib><creatorcontrib>Wang, Su-Na</creatorcontrib><creatorcontrib>Lu, Jing</creatorcontrib><creatorcontrib>Kong, Ling-Qian</creatorcontrib><creatorcontrib>Li, Da-Cheng</creatorcontrib><creatorcontrib>Dou, Jian-Min</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Qiu, Xiu-Min</au><au>Wang, Su-Na</au><au>Lu, Jing</au><au>Kong, Ling-Qian</au><au>Li, Da-Cheng</au><au>Dou, Jian-Min</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new linear trinuclear cobalt complex bearing oximato and azido ligands: synthesis, structure, and magnetic characterization</atitle><jtitle>Journal of coordination chemistry</jtitle><date>2012-09-20</date><risdate>2012</risdate><volume>65</volume><issue>18</issue><spage>3308</spage><epage>3315</epage><pages>3308-3315</pages><issn>0095-8972</issn><eissn>1029-0389</eissn><abstract>The reaction of CoCl
2
· 6H
2
O, mpkoH (methyl 2-pyridyl ketone oxime), NEt
3
, and NaN
3
in a 1 : 1 : 2 : 1 molar ratio affords a linear trinuclear complex, [
Co
II
(mpko)
4
(N
3
)
4
(H
2
O)
2
] (1). Complex 1 has been characterized by single-crystal X-ray diffraction, elemental analysis, and infrared spectrum. Three cobalt ions are in the center of distorted octahedra, which are connected by two μ-1,1 azides and two oxime oxygen atoms to form a linear trinuclear structure. Discrete units of 1 are connected to form a stable 3-D supramolecular network by C-H···O and C-H···N weak interactions. Variable temperature magnetic susceptibility measurements reveal that 1 exhibits antiferromagnetic behavior.</abstract><cop>Abingdon</cop><pub>Taylor & Francis Group</pub><doi>10.1080/00958972.2012.703779</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0095-8972 |
| ispartof | Journal of coordination chemistry, 2012-09, Vol.65 (18), p.3308-3315 |
| issn | 0095-8972 1029-0389 |
| language | eng |
| recordid | cdi_proquest_journals_1240567652 |
| source | Taylor and Francis Science and Technology Collection |
| subjects | Cobalt Cobalt complex Crystal structure Diffraction Distortion Ligands Magnetic permeability Magnetic properties Mineralogy Networks Oxime Oximes Three dimensional |
| title | A new linear trinuclear cobalt complex bearing oximato and azido ligands: synthesis, structure, and magnetic characterization |
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