Facile Access to Labdane-type Diterpenes: Synthesis of Coronarin C, Zerumin B, Labda-8(17), 13(14)-dien-15,16-olide and derivatives from (+)-manool

A practical method for the synthesis of optically active labdane-type diterpenes from (+)-manool 8, is described. We prepared the natural labdane-type diterpene 5 via key intermediate peroxide 9 and coronarin C 1, compound 8 and zerumin B 6 via a furan photosensitised oxygenation reactions.

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Bibliographic Details
Published in:Journal of chemical research 2007-06, Vol.2007 (6), p.342-346
Main Authors: Villamizar, José E., Juncosa, José, Pittelaud, Jean, Hernández, Madeleyn, Canudas, Nieves, Tropper, Eleonora, Salazar, Franklin, Fuentes, Juan
Format: Article
Language:English
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Description
Summary:A practical method for the synthesis of optically active labdane-type diterpenes from (+)-manool 8, is described. We prepared the natural labdane-type diterpene 5 via key intermediate peroxide 9 and coronarin C 1, compound 8 and zerumin B 6 via a furan photosensitised oxygenation reactions.
ISSN:1747-5198
2047-6507
DOI:10.3184/030823407X225527