Bis(chlorine)-1,4-Diazabicyclo[2.2.2]Octane: A Novel and Reusable Oxidising Agent for Conversion of Alcohols into Their Carbonyl Compounds under Microwave Irradiation

Bis(chlorine)-1,4-diazabicyclo[2.2.2]octane was easily prepared by treatment of chlorine gas with 1,4-diazabicyclo [2.2.2]octane at room temperature. It is stable and can be used as an efficient oxidant for aliphatic and aromatic alcohols under microwave irradiation. In the oxidation reactions it is...

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Bibliographic Details
Published in:Journal of chemical research 2006-08, Vol.2006 (8), p.539-541
Main Authors: Tajbakhsh, Mahmood, Habibzadeh, Setareh
Format: Article
Language:English
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Summary:Bis(chlorine)-1,4-diazabicyclo[2.2.2]octane was easily prepared by treatment of chlorine gas with 1,4-diazabicyclo [2.2.2]octane at room temperature. It is stable and can be used as an efficient oxidant for aliphatic and aromatic alcohols under microwave irradiation. In the oxidation reactions it is almost quantitatively converted into 1,4-diazabicyclo[2.2.2]octane which can be chlorinated and reused several times.
ISSN:1747-5198
2047-6507
DOI:10.3184/030823406778256487