Back Cover: A Multispectroscopic Study of 3dOrbitals in Cobalt Carboxylates: The High Sensitivity of 2p3d Resonant X-ray Emission Spectroscopy to the Ligand Field (Angew. Chem. Int. Ed. 4/2013)

d-d excitations in detail: High-resolution 2p3d resonant X-ray emission spectroscopy (RXES) allows the observation of more as well as more intense d-d excitations than UV/Vis spectroscopy does as demonstrated on cobalt(II) carboxylates. Together with ligand field multiplet (LFM) calculations this al...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2013-01, Vol.52 (4), p.1170
Main Authors: vanSchooneveld, Matti M, Gosselink, Robert W, Eggenhuisen, Tamara M, AlSamarai, Mustafa, Monney, Claude, Zhou, Kejin J, Schmitt, Thorsten, deGroot, Frank M. F
Format: Article
Language:English
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Summary:d-d excitations in detail: High-resolution 2p3d resonant X-ray emission spectroscopy (RXES) allows the observation of more as well as more intense d-d excitations than UV/Vis spectroscopy does as demonstrated on cobalt(II) carboxylates. Together with ligand field multiplet (LFM) calculations this allows their detailed electronic structure description, while 2p X-ray absorption spectroscopy (XAS) cannot discriminate these transition metal compounds.
ISSN:1433-7851
1521-3773