Nanocomposite polymer electrolytes membranes based on Poly(vinylphosphonic acid)/SiO2

Proton conducting polymer electrolytes bearing phosphonic acid units are very promising due to their high conductivity, thermal and chemical stability. In the present work, proton conducting nanocomposite electrolytes containing poly(vinylphosphonic acid) (PVPA) and SiO 2 were prepared by two differ...

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Published in:Journal of polymer research 2012-12, Vol.19 (12), p.1, Article 22
Main Authors: Aslan, Ayşe, Gölcük, Kurtuluş, Bozkurt, Ayhan
Format: Article
Language:English
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Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Original Paper
Polymer Sciences
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description Proton conducting polymer electrolytes bearing phosphonic acid units are very promising due to their high conductivity, thermal and chemical stability. In the present work, proton conducting nanocomposite electrolytes containing poly(vinylphosphonic acid) (PVPA) and SiO 2 were prepared by two different methods. The interaction existed between PVPA and SiO 2 was confirmed by FT-IR spectroscopy. The surface roughness of the nanocomposites was studied using AFM. Thermogravimetric analysis revealed that the samples were thermally stable up to 200 °C. The glass transition temperature (Tg) of the materials were determined using DSC. In the anhydrous state, the proton conductivity of PVPA(10)SiO 2 (in situ) was found to be 0,009 (Scm −1 ) at 120 °C. The proton conductivity of PVPA(10)SiO 2 increased to 0.08 (Scm −1 ) at 50 % relative humidity. The SiO 2 nanoparticles in the composite membranes improved the thermal properties and increased the proton conductivity.
doi_str_mv 10.1007/s10965-012-0022-3
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subjects Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Original Paper
Polymer Sciences
title Nanocomposite polymer electrolytes membranes based on Poly(vinylphosphonic acid)/SiO2
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