Achieving organic nanoparticles with redox-active capabilities: synthesis of gold nanoparticles in water as a proof-of-principle

Herein, we present a unique approach to easily achieve redox-active nanosized organic particles in aqueous environment using a strategy based on ion association between large organic ions, namely tetraphenylborate anions and thiazole orange cations. The anionic tetraphenylborate associates tightly w...

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Published in:Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology 2012-09, Vol.14 (9), p.1, Article 1099
Main Authors: Mooi, Sara M., Sutherland, Todd C., Heyne, Belinda
Format: Article
Language:English
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Anions
Brief Communication
Cations
Characterization and Evaluation of Materials
Chemistry and Materials Science
Inorganic Chemistry
Lasers
Materials Science
Nanoparticles
Nanotechnology
Optical Devices
Optics
Photonics
Physical Chemistry
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cited_by cdi_FETCH-LOGICAL-c316t-ed031dcfc5c919b3e68640e0a6b95e4634222c1dca4751deef1acededc5347cc3
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description Herein, we present a unique approach to easily achieve redox-active nanosized organic particles in aqueous environment using a strategy based on ion association between large organic ions, namely tetraphenylborate anions and thiazole orange cations. The anionic tetraphenylborate associates tightly with the cationic redox-active thiazole orange producing a well-defined meta-stable organic nanoscale particle (73 ± 20 nm). These redox-active nanosized organic particles can act as seed sites for metal reductions and as a proof-of-concept, they were used to reduce gold(III) to gold nanoparticles in a neutral, aqueous environment at room temperature.
doi_str_mv 10.1007/s11051-012-1099-7
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source Springer Nature
subjects Anions
Brief Communication
Cations
Characterization and Evaluation of Materials
Chemistry and Materials Science
Inorganic Chemistry
Lasers
Materials Science
Nanoparticles
Nanotechnology
Optical Devices
Optics
Photonics
Physical Chemistry
title Achieving organic nanoparticles with redox-active capabilities: synthesis of gold nanoparticles in water as a proof-of-principle
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