Microwave assisted hydrothermal synthesis of mesoporous SnO2 nanoparticles for ethanol sensing and degradation

• Published in: Journal of materials science. Materials in electronics 2013-06, Vol.24 (6), p.2082-2090
• Main Authors: Tripathy, Suraj K., Mishra, Amrita, Jha, Sandeep Kumar, Wahab, Rizwan, Al-Khedhairy, Abdulaziz A.
• Format: Article
• Language: English
• Subjects: Applied sciences; Characterization and Evaluation of Materials; Chemistry and Materials Science; Cross-disciplinary physics: materials science; rheology; Electronics; Exact sciences and technology; Fractures; General equipment and techniques; Instruments, apparatus, components and techniques common to several branches of physics and astronomy; Materials; Materials Science; Mechanical properties and methods of testing. Rheology. Fracture mechanics. Tribology; Metals. Metallurgy; Nanopowders; Nanoscale materials and structures: fabrication and characterization; Optical and Electronic Materials; Physics; Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing
• ISSN: 0957-4522; 1573-482X
• DOI: 10.1007/s10854-013-1062-0

We report the synthesis of mesoporous SnO 2 nanoparticles by a microwave assisted hydrothermal process and their application as a gas sensor. The synthesized materials were characterized by transmission electron microscopy, X-ray diffraction technique, X-ray photoelectron spectroscopy, and Photoluminescence spectroscopy. As the results, we found that as-synthesized SnO 2 was synthetic Cassiterite with tetragonal structure and spherical in shape with the primary crystallite size of 6–8 nm, and the SnO 2 embedded material was mesoporous with average pore sizes of ≈15 nm. Moreover, this material showed excellent thermal stability from 80 to 800 °C and its crystal structure after heat treatment was preserved even at ultrahigh temperature of 800 °C. We demonstrated that this material could be used for detection of the ethanol gas because of its stability and nanoscale size at high temperature. Additionally our investigations also suggest that the processed materials can be used for the photocatalytic oxidation of ethanol. These results propose the potential application of the material for a sense and shoot kind of approach for indoor air purification in pharmaceutical and fermentation monitoring and vehicular control through breath analyzer.